STUDY OF NON-FUEL APPLICATION OF BROWN COAL DERIVATIVES FOR BITUME MODIFICATION

V. Lebedev, D. Miroshnichenko, I. Lavrova, A. N. Cherkashina
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Abstract

The article shows research into the non-fuel use of brown coal derivatives for the modification of bitumen. The work used petroleum road grade bitumen BND 60/90 with a flash point in an open crucible of 260 °C, a softening temperature (using the ring and ball method) of 48 °C, resin after lignite thermal destruction and rubber waste. and powder. Based on the fact that the most relevant technologies for the non-fuel use of brown coal concern areas aimed at obtaining wax, humane preparations, adsorbents, obtaining valuable derivatives in the form of resins, GR, etc., an assessment was made of the non-fuel use of brown coal derivatives for modification bitumen. Analysis of the experimental results showed that the studied quality indicators of the composition samples, which include waste rubber powder, have an increased complex of both thermophysical and physical-mechanical characteristics. This is obviously due to the fact that, as a result of thermal destruction of rubber powder, the swelling process occurs faster compared to crumb rubber with a size of 2.5–4.5 mm. However, the process of destruction and dispersion in both cases does not occur completely, of course, and the volume of edematous rubber particles contains resins and polyaromatic components that affect the value of both thermophysical and physical-mechanical characteristics. Thus, it has been established that the optimal composition for creating effective polymer-modified bitumens with an increased complex of thermo-physical and physical-mechanical characteristics is 40 % by weight of rubber powder and 5 % by weight. brown coal resins after thermal destruction. It is shown that the results of laboratory studies have proven the prospects of using brown coal tar after thermal destruction for the modification of road bitumen. Summarizing research into the direction of non-fuel use of brown coal derivatives in the form of liquid products – tar resins of brown coal after thermal destruction for the modification of bitumen materials, it should be noted that the results obtained are moderate in comparison with existing directions for the production of polymer-modified bitumens. Modification of bitumen with primary and secondary polymers makes it possible to significantly improve their adhesion and performance characteristics compared to brown coal resins after thermal destruction. The use of brown coal resins after thermal destruction is much less effective in improving the elasticity, heat resistance and reducing the fragility of bitumen compositions compared to the use of thermoplastic and thermoelastomer modifiers in the production of polymer-modified bitumens.
褐煤衍生物在非燃料应用中的比特米改性研究
文章介绍了对褐煤衍生物用于改性沥青的非燃料用途的研究。该研究使用了石油公路级沥青 BND 60/90(在开放式坩埚中的闪点为 260 °C,软化温度(使用环和球方法)为 48 °C)、褐煤热销毁后的树脂以及橡胶废料和粉末。褐煤非燃料利用的最相关技术涉及蜡、人性化制剂、吸附剂、树脂形式的有价值衍生物、GR 等领域,基于这一事实,对改性沥青褐煤衍生物的非燃料利用进行了评估。对实验结果的分析表明,所研究的包括废橡胶粉在内的成分样品的质量指标具有更复杂的热物理和物理机械特性。这显然是由于橡胶粉热破坏的结果,与尺寸为 2.5-4.5 毫米的橡胶屑相比,膨胀过程发生得更快。然而,这两种情况下的破坏和分散过程当然不会完全发生,水肿橡胶颗粒的体积中含有树脂和多芳烃成分,这些成分会影响热物理和物理机械特性的值。因此,已经确定,要制造出具有更高的热物理和物理机械特性复合体的有效聚合物改性沥青,其最佳成分为 40% (按重量计)橡胶粉和 5% (按重量计)热破坏后的褐煤树脂。实验室研究结果表明,热破坏后的褐煤焦油具有改性路面沥青的前景。在总结对液态产品形式的褐煤衍生物--热破坏后的褐煤焦油树脂--的非燃料使用方向的研究以改性沥青材料时,应该注意到,与现有的聚合物改性沥青生产方向相比,所获得的结果是适中的。与热破坏后的褐煤树脂相比,用一级和二级聚合物对沥青进行改性可显著改善其粘附性和性能特征。与使用热塑性和热弹性体改性剂生产聚合物改性沥青相比,使用热破坏后的褐煤树脂在改善沥青组合物的弹性、耐热性和降低脆性方面的效果要差得多。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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