Sanjukta Pahar, Aleksandra Górecka, Emma Richards, Rebecca L. Melen
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引用次数: 0
Abstract
Due to the upswing in interest in the development of efficient hydroelementation reactions to construct C–heteroatom bonds either stoichiometrically or catalytically, the activation of isocyanates and isothiocyanates has received recent attention. The activation and derivatization of isocyanates and isothiocyanates using earth-abundant and inexpensive group 13 main-group compounds have lately been observed more frequently. In this review, we aim to highlight the activation of the C=N vs. C=O and C=S bonds, the scope of cycloaddition reactions of iso(thio)cyanates with group 13 compounds, and recent findings using frustrated Lewis pairs (FLPs). In addition, the hydroboration and hydroamination reactions of these substrates are also discussed to formulate synthetically important urea/amide or thioamide derivatives.
期刊介绍：
Cell Reports Physical Science, a premium open-access journal from Cell Press, features high-quality, cutting-edge research spanning the physical sciences. It serves as an open forum fostering collaboration among physical scientists while championing open science principles. Published works must signify significant advancements in fundamental insight or technological applications within fields such as chemistry, physics, materials science, energy science, engineering, and related interdisciplinary studies. In addition to longer articles, the journal considers impactful short-form reports and short reviews covering recent literature in emerging fields. Continually adapting to the evolving open science landscape, the journal reviews its policies to align with community consensus and best practices.
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