MOF thin film memristor prototype of 10×10 memory cells for automated electronic data recording

IF 2.5 3区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Semyon V. Bachinin, Anastasia Lubimova, Artem Polushkin, Sergei S. Rzhevskii, Maria Timofeeva, Valentin A. Milichko
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引用次数: 0

Abstract

Metal–organic frameworks (MOFs) have recently emerged as a new class of functional materials for opto- and micro-electronic applications. Herein, the transition from laboratory samples of devices to their prototypes remains a challenge. Here we report a prototype of memristive device based on MOF (HKUST-1). The MOF thin film with a thickness of 130 nm and a size of 1 × 1 in. has been fabricated Layer-by-layer technique on a conductive substrate followed by the deposition of top Ag contacts. A fully automated process of applying voltage to write the binary data (at 0.8 ± 0.1 V), read it (by 0.4 V) and then erase (by inverted polarity with 0.4 ± 0.1 V) made it potentially possible to process arbitrary words for at least 10 cycles. The provided prototype, consisting of 10 × 10 memory cells, opens up prospects for real-life application of MOF-based logic elements, as well as reveals the challenges for their fabrication and exploitation.

用于自动电子数据记录的 10×10 存储单元的 MOF 薄膜忆阻器原型
金属有机框架(MOFs)近来已成为光电子和微电子应用领域的一类新型功能材料。在这方面,从实验室样品到器件原型的过渡仍然是一个挑战。在此,我们报告了基于 MOF 的忆阻器件原型(HKUST-1)。我们采用逐层技术在导电基底上制作了厚度为 130 nm、大小为 1×1 英寸的 MOF 薄膜,然后沉积了顶部的银触点。通过全自动过程:施加电压写入二进制数据(0.8 ± 0.1 V)、读取(0.4 V)和擦除(0.4 ± 0.1 V 的反极性),可以处理任意字至少 10 个周期。所提供的原型由 10×10 个存储单元组成,为基于 MOF 的逻辑元件在现实生活中的应用开辟了前景,同时也揭示了其制造和利用所面临的挑战。
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来源期刊
CiteScore
5.00
自引率
3.70%
发文量
77
审稿时长
62 days
期刊介绍: This journal establishes a dedicated channel for physicists, material scientists, chemists, engineers and computer scientists who are interested in photonics and nanostructures, and especially in research related to photonic crystals, photonic band gaps and metamaterials. The Journal sheds light on the latest developments in this growing field of science that will see the emergence of faster telecommunications and ultimately computers that use light instead of electrons to connect components.
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