Source and significance of Cretaceous oil seepage in the northern Ordos Basin, China

IF 2.6 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Mai Zhang , Daofu Song , Tieguan Wang , Faqi He , Wei Zhang , Chuan An , Anliang Liu , Jiadong Yan
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Abstract

It has long been believed that the region on the north of the Dongsheng gas field has only limited exploration potential due to the lack of effective source rocks. However, several areas of Cretaceous oil seepage have been discovered in the area and their sources are unclear. In this study, the organic geochemical characteristics of these oil seepages and potential source rocks (coals and carbonaceous mudstones of different formations) are examined using TOC analysis, pyrolysis, gas chromatography-mass spectrometry, and carbon isotopes. The results show that the oil seepages are low-to-moderately mature (0.63 %-0.78 % Rc) and slightly biodegraded. The molecular biomarker compositions of the oil seepages are characterized by C29≫C28>C27 normalized relative abundance of regular steranes, high values of Pr/Ph, (C19TT + C20TT)/C23TT and C24TeT/C26TT ratios, low values of Ga/C30H, and low abundance of dibenzothiophenes. The biomarker compositions, as well as the stable carbon isotopes, indicate that the source of the oil seepages was deposited in a lacustrine fluvial/deltaic environment under oxic to sub-oxic conditions, with organic matter input predominantly from terrigenous higher plants. Oil-source correlation revealed that the oil seepages were closely related to the coals in the Shanxi formation in the south source kitchen, implying that the hydrocarbons generated in the south source kitchen have been able to migrate to the north edge of the Ordos Basin. The oil seepages are accompanied by significant gas leakage. The zone between the Dongsheng gas field and the Wulangar Uplift is therefore likely to have very good accumulation and preservation conditions and may offer a promising exploration prospect for natural gas.

中国鄂尔多斯盆地北部白垩纪石油渗流的来源和意义
长期以来,人们一直认为,由于缺乏有效的源岩,东胜气田北部地区的勘探潜力有限。然而,该地区已发现多处白垩系渗油,其来源尚不清楚。本研究采用 TOC 分析、热解、气相色谱-质谱法和碳同位素等方法研究了这些渗油区和潜在源岩(不同地层的煤和碳质泥岩)的有机地球化学特征。结果表明,渗出油层的成熟度从低到中等(0.63 %-0.78 % Rc),并略有生物降解。渗出油层的分子生物标志物组成特点是:C29≫C28>C27 归一化的常规甾烷相对丰度、高 Pr/Ph、(C19TT + C20TT)/C23TT 和 C24TeT/C26TT 比值、低 Ga/C30H 值以及低丰度的二苯并噻吩。生物标记物组成以及稳定碳同位素表明,渗漏油的来源是在缺氧至亚缺氧条件下沉积在湖泊河道/三角洲环境中的,有机物质主要来自陆生高等植物。油源相关性显示,渗油与南源厨房山西地层中的煤密切相关,这意味着南源厨房产生的碳氢化合物能够迁移到鄂尔多斯盆地的北缘。石油渗漏伴随着大量的天然气渗漏。因此,东胜气田与乌兰格尔隆起带之间的区域可能具有很好的积聚和保存条件,并可能为天然气勘探提供广阔的前景。
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来源期刊
Organic Geochemistry
Organic Geochemistry 地学-地球化学与地球物理
CiteScore
5.50
自引率
6.70%
发文量
100
审稿时长
61 days
期刊介绍: Organic Geochemistry serves as the only dedicated medium for the publication of peer-reviewed research on all phases of geochemistry in which organic compounds play a major role. The Editors welcome contributions covering a wide spectrum of subjects in the geosciences broadly based on organic chemistry (including molecular and isotopic geochemistry), and involving geology, biogeochemistry, environmental geochemistry, chemical oceanography and hydrology. The scope of the journal includes research involving petroleum (including natural gas), coal, organic matter in the aqueous environment and recent sediments, organic-rich rocks and soils and the role of organics in the geochemical cycling of the elements. Sedimentological, paleontological and organic petrographic studies will also be considered for publication, provided that they are geochemically oriented. Papers cover the full range of research activities in organic geochemistry, and include comprehensive review articles, technical communications, discussion/reply correspondence and short technical notes. Peer-reviews organised through three Chief Editors and a staff of Associate Editors, are conducted by well known, respected scientists from academia, government and industry. The journal also publishes reviews of books, announcements of important conferences and meetings and other matters of direct interest to the organic geochemical community.
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