Comparison of the Hydrocarbon Distribution in Thermolysis Products of Asphaltenes, Resins, and Acids Isolated from Weakly Transformed Crude Oil from the Anastasievsko-Troitskoe Oil Field (Horizon IV)
G. N. Gordadze, A. V. Vasileva, D. S. Vylekzhanina, G. A. Gadzhiev, O. A. Stokolos
{"title":"Comparison of the Hydrocarbon Distribution in Thermolysis Products of Asphaltenes, Resins, and Acids Isolated from Weakly Transformed Crude Oil from the Anastasievsko-Troitskoe Oil Field (Horizon IV)","authors":"G. N. Gordadze, A. V. Vasileva, D. S. Vylekzhanina, G. A. Gadzhiev, O. A. Stokolos","doi":"10.1134/S0965544123060130","DOIUrl":null,"url":null,"abstract":"<p>Regular trends in the distribution of hydrocarbon biomarkers (<i>n</i>-alkanes, isoprenanes, steranes, and terpanes) and hydrocarbons of the adamantane series in low-maturity crude oil from the Anastasievsko-Troitskoe oil field (horizon IV) and in products formed by thermolysis of asphaltenes, resins, and acids from this oil were studied by gas chromatography–mass spectrometry. Thermolysis of high-molecular-mass oil precursors yields the same hydrocarbons (HCs) as those present in the initial oil, and also protoadamantanes (precursors of adamantanes). HCs of the adamantane series are not formed, and their presence in this crude oil is due to their supply from other oil source strata. The experiments show that the <i>n</i>-alkanes present in the initial oil in small amounts are released under more severe conditions.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0965544123060130","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Regular trends in the distribution of hydrocarbon biomarkers (n-alkanes, isoprenanes, steranes, and terpanes) and hydrocarbons of the adamantane series in low-maturity crude oil from the Anastasievsko-Troitskoe oil field (horizon IV) and in products formed by thermolysis of asphaltenes, resins, and acids from this oil were studied by gas chromatography–mass spectrometry. Thermolysis of high-molecular-mass oil precursors yields the same hydrocarbons (HCs) as those present in the initial oil, and also protoadamantanes (precursors of adamantanes). HCs of the adamantane series are not formed, and their presence in this crude oil is due to their supply from other oil source strata. The experiments show that the n-alkanes present in the initial oil in small amounts are released under more severe conditions.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
