Evolution of Organometallasiloxanes

IF 1.6 4区 化学 Q4 POLYMER SCIENCE
A. A. Anisimov, E. O. Minyaylo, A. R. Shakirova, O. I. Shchegolikhina
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引用次数: 0

Abstract

The development of organometallasiloxane chemistry from first polymeric systems to individual organometallasiloxanes and functional oligomeric compounds is considered. The structural diversity of organosilicon precursors and the variability of metal-containing components are presented. Synthetic approaches are considered in detail, including those that allow targeted production of organometallasiloxanes of a certain structure. Using the example of organometallasiloxanes synthesized from trifunctional organoalkoxysilanes, methods for the synthesis of unique stereoregular functional cyclosiloxanes and their derivatives are highlighted. Considerable attention is given to the applied aspects of various structure organometallasiloxanes and their derivatives. The state of the art of the chemistry of organometallasiloxanes and their further evolution are evaluated critically.

Abstract Image

Abstract Image

有机金属硅氧烷的演化
摘要综述了有机金属硅氧烷化学从最初的聚合物体系到单个有机金属硅氧烷和功能性低聚化合物的发展历程。介绍了有机硅前驱体的结构多样性和含金属组分的可变性。详细考虑了合成方法,包括那些允许有针对性地生产某种结构的有机金属硅氧烷的方法。以三官能团有机烷氧基硅烷合成有机金属硅氧烷为例,重点介绍了独特的立体规则官能团环硅氧烷及其衍生物的合成方法。对各种结构的有机金属硅氧烷及其衍生物的应用方面给予了相当的关注。对有机金属硅氧烷的化学现状及其进一步发展进行了评述。
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来源期刊
Polymer Science, Series C
Polymer Science, Series C 工程技术-高分子科学
CiteScore
3.00
自引率
4.50%
发文量
21
审稿时长
>12 weeks
期刊介绍: Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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