A Review of Traditional and Intensified Hydrometallurgy Techniques to Remove Chromium and Vanadium from Solid Industrial Waste

IF 4.3 Q2 ENGINEERING, CHEMICAL
Aya Saidi, Rebecca El Khawaja and Daria C. Boffito*, 
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Abstract

The continuous growth of industrial activities, driven by economic expansion and technological advancements, has increased industrial waste generation. These wastes often contain hazardous substances, including heavy metals. Their improper disposal has become a significant environmental and health concern, necessitating global attention. To address this issue and mitigate the scarcity and cost of raw materials, recycling waste materials has emerged as a viable solution, particularly in the synthesis of construction materials. Various methods, such as pyrometallurgical and hydrometallurgical techniques, have been established for recycling industrial waste. This Review focuses on hydrometallurgical techniques, specifically targeting the separation of two highly toxic heavy metals: chromium and vanadium. It comprehensively explores various hydrometallurgical methods, including acid, alkaline, organic, and oxidative leaching, for solid waste materials. Additionally, this Review highlights several intensified leaching processes assisted by electrical fields, supercritical fluids, plasma, microwaves, and ultrasound. The presented methods offer promising approaches to effectively manage industrial waste.

Abstract Image

Abstract Image

传统和强化湿法冶金法去除固体工业废物中铬、钒的研究进展
在经济扩张和技术进步的推动下,工业活动的不断增长增加了工业废物的产生。这些废物通常含有有害物质,包括重金属。它们的不当处置已成为一个重大的环境和健康问题,需要引起全球注意。为了解决这一问题并减轻原材料的稀缺和成本,回收废料已成为一种可行的解决方案,特别是在建筑材料的合成方面。各种方法,如火法冶金和湿法冶金技术,已经建立了回收工业废物。本文综述了湿法冶金技术的研究进展,重点介绍了两种高毒性重金属铬和钒的分离。全面探讨了固体废物的酸浸、碱浸、有机浸、氧化浸等湿法冶金方法。此外,本综述还重点介绍了几种由电场、超临界流体、等离子体、微波和超声波辅助的强化浸出过程。所提出的方法为有效管理工业废物提供了有前途的途径。
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来源期刊
ACS Engineering Au
ACS Engineering Au 化学工程技术-
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期刊介绍: )ACS Engineering Au is an open access journal that reports significant advances in chemical engineering applied chemistry and energy covering fundamentals processes and products. The journal's broad scope includes experimental theoretical mathematical computational chemical and physical research from academic and industrial settings. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Fundamental research in such areas as thermodynamics transport phenomena (flow mixing mass & heat transfer) chemical reaction kinetics and engineering catalysis separations interfacial phenomena and materialsProcess design development and intensification (e.g. process technologies for chemicals and materials synthesis and design methods process intensification multiphase reactors scale-up systems analysis process control data correlation schemes modeling machine learning Artificial Intelligence)Product research and development involving chemical and engineering aspects (e.g. catalysts plastics elastomers fibers adhesives coatings paper membranes lubricants ceramics aerosols fluidic devices intensified process equipment)Energy and fuels (e.g. pre-treatment processing and utilization of renewable energy resources; processing and utilization of fuels; properties and structure or molecular composition of both raw fuels and refined products; fuel cells hydrogen batteries; photochemical fuel and energy production; decarbonization; electrification; microwave; cavitation)Measurement techniques computational models and data on thermo-physical thermodynamic and transport properties of materials and phase equilibrium behaviorNew methods models and tools (e.g. real-time data analytics multi-scale models physics informed machine learning models machine learning enhanced physics-based models soft sensors high-performance computing)
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