Iron-catalyzed sulfur alkylation of sulfenamides with in situ-generated 2,2,2-trifluorodiazoethane

IF 1.7 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2023-11-23 DOI:10.1016/j.jfluchem.2023.110219

Xianda Wu , Minghong Chen , Shuiyun Zheng , Fu-Sheng He , Jie Wu

引用次数: 0

Abstract

Herein, we report an iron-catalyzed sulfur alkylation between sulfenamides and in situ-generated 2,2,2-trifluorodiazoethane to access sulfilimines. This protocol involves the use of inexpensive PcFe as the catalyst. The reaction features operational simplicity, mild conditions and open air, providing a facile approach to trifloromethylated sulfilimines in moderate to good yields.

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铁催化磺胺类与原位生成的2,2,2-三氟重氮乙烷的硫烷基化反应

在这里，我们报道了铁催化的硫烷基化在亚砜酰胺和原位生成的2,2,2-三氟重氮乙烷之间得到亚砜胺。该方案涉及使用廉价的PcFe作为催化剂。该反应具有操作简单、条件温和、露天等特点，为中高收率的三氟甲基化亚胺提供了一种简便的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.