A mechanical derivation of the evolution equation for scintillating crystals: Recombination–diffusion–drift equations, gradient flows and Wasserstein measures

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Fabrizio Daví
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引用次数: 0

Abstract

In a series of previous papers we obtained, by the means of the mechanics of continua with microstructure, the Reaction–Diffusion–Drift equation which describes the evolution of charge carriers in scintillators. Here we deal, first of all, with the consequences of constitutive assumptions for the entropic and dissipative terms. In the case of Boltzmann–Gibbs entropy, we show that the equation admits a gradient flows structure: moreover, we show that the drift–diffusion part is a Wasserstein gradient flow and we show how the energy dissipation is correlated with an appropriate Wasserstein distance.

闪烁晶体演化方程的力学推导:重组-扩散-漂移方程、梯度流和瓦瑟斯坦测量
在之前的一系列论文中,我们利用微观连续体力学得到了描述闪烁体中载流子演化的反应-扩散-漂移方程。在这里,我们首先处理本构假设对熵项和耗散项的影响。在Boltzmann-Gibbs熵的情况下,我们证明了方程允许梯度流动结构;此外,我们证明了漂移-扩散部分是一个Wasserstein梯度流动,我们证明了能量耗散如何与适当的Wasserstein距离相关。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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