Modulating contact properties by molecular layers in organic thin-film transistors

Electron Pub Date : 2023-09-20 DOI:10.1002/elt2.7
Li Sun, Yating Li, Jiacheng Xie, Liqi Zhou, Peng Wang, Jian-Bin Xu, Yi Shi, Xinran Wang, Daowei He
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Abstract

Advanced organic devices and circuits demand both ultrahigh charge carrier mobilities and ultralow-resistance contacts. However, due to a larger access resistance in staggered organic thin-film transistors (OTFTs), the achievement of ultralow contact resistance () is still a challenge. The modulation of contact resistance by molecular layers near the interface has been rarely reported. Here, we demonstrate that few-layer organic single crystals are grown on hafnium oxide (HfO2) by solution-shearing epitaxy. We utilize these organic crystals to fabricate bottom-gate staggered OTFTs with different contact processes. The results show that the contact properties of OTFTs are obviously modulated by crystal layers. The tri-layer (3L) evaporated-Au C10-DNTT OTFTs exhibit optimal electrical performance, including ultralow of 5.6 Ω ∙ cm, recorded transfer length of 0.4 μm, field-effect mobility over 14 , threshold voltage lower than 0.3 V, and long-term air stability over 8 months. The main cause is that the metal atoms can penetrate into the charge transport layer, with damage-free, in 3L evaporated-Au OTFTs; nevertheless, it cannot be realized in other cases. Due to layer stacking of conjugated molecules and polymers, our strategy can efficiently modulate the contact resistance to aid the development of high-performance organic devices and circuits.

Abstract Image

用分子层调制有机薄膜晶体管的接触特性
先进的有机器件和电路需要超高的载流子迁移率和超低电阻接触。然而,由于交错有机薄膜晶体管(OTFTs)中较大的接触电阻,实现超低接触电阻()仍然是一个挑战。界面附近分子层对接触电阻的调制很少有报道。在这里,我们证明了通过溶液剪切外延在氧化铪(HfO 2)上生长出了几层有机单晶。我们利用这些有机晶体来制造具有不同接触工艺的底栅交错otft。结果表明,晶体层对OTFTs的接触特性有明显的调制作用。三层(3L)蒸发- Au - C - 10 - DNTT OTFTs具有最佳的电学性能,包括超低5.6 Ω∙cm,记录的转移长度为0.4 μm,场效应迁移率超过14,阈值电压低于0.3 V,以及超过8个月的长期空气稳定性。主要原因是在3L蒸发- Au otft中,金属原子可以无损伤地穿透到电荷输运层;然而,在其他情况下则无法实现。由于共轭分子和聚合物的层堆叠,我们的策略可以有效地调节接触电阻,以帮助开发高性能有机器件和电路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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