Development of compositions of slag-alkaline binding materials for pavement products

Q4 Chemistry
G.M. Shabanova, A.M. Korogodska, V.M. Shumeiko, O.M. Borysenko, G.V. Lisachuk, R.V. Kryvobok, M.D. Sakhnenko
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Abstract

In this work, blast furnace granulated slag of the Kamet-Stal plant was investigated. It was established that the slag belongs to the basic ones. According to the quality factor, the slag belongs to grade 1 and can be used to fabricate slag-alkaline binding material by the alkaline method of activation. A significant part of the slag is in an X-ray amorphous state, which contributes to the production of strong cement stone in the late stages of hardening. The crystalline phases of the slag exhibit weak binding properties and provide strength to the hardened slag-alkaline binding material. To activate the slag and plasticize the composition, portland cement and clay were introduced into it, sodium liquid glass, caustic soda solution and soda ash solution being used as an alkaline sealer. The exclusion of clay from the basic composition leads to an increase in strength almost twice due to additional activation of slag with portland cement. A significant drawback in this case is the numerous precipitates that appear on the samples already on the first day of hardening. Thus, for accelerated curing times, increased mechanical strength, reduction in the amount of leaching and a significant reduction in the cost of finished products, we suggested the composition containing 91 wt.% slag; 6 wt.% clay; and 3 wt.% portland cement closed with a solution of liquid glass with a modulus of 2.3 and a density of 1300 kg/m3.
路面用渣碱粘结材料的研制
本文以Kamet-Stal厂的高炉颗粒渣为研究对象。确定该渣属碱性渣。根据质量因数,该矿渣为一级矿渣,可采用碱性活化法制备矿渣-碱结合材料。渣中有相当一部分处于x射线无定形状态,这有助于在硬化后期形成较强的水泥石。渣的结晶相表现出弱结合特性,并为硬化的渣碱结合材料提供了强度。为使矿渣活化和塑化,在矿渣中掺入硅酸盐水泥和粘土,用钠液玻璃、烧碱溶液和纯碱溶液作为碱性密封剂。从基本成分中除去粘土,由于矿渣与硅酸盐水泥的额外活化,强度几乎增加了两倍。在这种情况下,一个重要的缺点是在硬化的第一天就已经在样品上出现了大量的沉淀。因此,为了加速固化时间、提高机械强度、减少浸出量和显著降低成品成本,我们建议使用含有91 wt.%矿渣的组合物;6 wt.%粘土;3wt .%的波特兰水泥与模量为2.3、密度为1300kg /m3的液态玻璃溶液封闭。
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来源期刊
Voprosy Khimii i Khimicheskoi Tekhnologii
Voprosy Khimii i Khimicheskoi Tekhnologii Chemical Engineering-Chemical Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
62
期刊介绍: Voprosy Khimii i Khimicheskoi Tekhnologii (Issues of Chemistry and Chemical Technology) is published bimonthly by the Ukrainian State University of Chemical Technology and accepts Ukrainian- or English language high-quality original articles and reviews concerning various fields of research in chemistry and chemical engineering. Our unusual title “Voprosy khimii i khimicheskoi tekhnologii” originates from the transliterated initial Russian title “Issues of Chemistry and Chemical Technology“. The fact of the matter is that Voprosy khimii i khimicheskoi tekhnologii was founded in 1965 as a scientific journal mainly for Russian-reading and Russian-speaking readership when «the Iron Curtain» existed. Since 1991, after Ukraine declared its independence, our Journal began to publish the articles in Ukrainian and English. Multilingualism is our established tradition. We remember and cherish our traditions, but we follow the latest trends in modern science. Papers that are multidisciplinary or address new or emerging areas of chemistry and chemical engineering are particularly encouraged. Thus, the scope is dynamic. It includes but is not limited to the traditional areas of general, inorganic, organic, analytical, physical chemistry and electrochemistry, as well as all conventional areas of chemical engineering (chemistry of high molecular compounds, technology of inorganic and organic substances, processing of combustible minerals, chemical technology of silicates, processes and apparatus of chemical productions, etc.). The Journal publishes papers dealing with newer interdisciplinary areas such as materials science, nano-science, catalysis, computational and theoretical chemistry, surface phenomenon and colloidal systems, environmental chemistry, green chemistry.
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