The feasibility of utilizing microwave-assisted pyrolysis for Albizia branches biomass conversion into biofuel productions

Maha Faisal Abd, Atheer Mohammed Al-Yaqoobi
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Abstract

The consumption of fossil fuels has caused many challenges, including environmental and climate damage, global warming, and rising energy costs, which has prompted seeking to substitute other alternative sources. The current study explored the microwave pyrolysis of Albizia branches to assess its potential to produce all forms of fuel (solid, liquid, gas), time savings, and effective thermal heat transfer. The impact of the critical parameters on the quantity and quality of the biofuel generation, including time, power levels, biomass weight, and particle size, were investigated. The results revealed that the best bio-oil production was 76% at a power level of 450 W and 20 g of biomass. Additionally, low power levels led to enhanced biochar production, where a percentage of 70% appeared when employing a power level of 300 W. Higher power levels were used to increase the creation of gaseous fuels in all circumstances, such as in 700 W, the gas yield was 31%. The density, viscosity, acidity, HHV, GC-MS, and FTIR instruments were used to analyze the physical and chemical characteristics of the bio-oil. The GC-MS analysis showed that the bio-oil consists of aromatic compounds, ketones, aldehydes, acids, esters, alkane, alkenes and heterocyclic compounds. The most prevalent component was aromatic compounds with 12.79% and ketones with 12.15%, while the pH of the oil obtained was 5, and the HHV was 19.5 MJ/kg. The pyrolysis productions could be promising raw materials for different applications after further processing.
利用微波辅助热解将合欢枝生物质转化为生物燃料的可行性
化石燃料的消耗带来了许多挑战,包括环境和气候破坏、全球变暖以及能源成本上升,这促使人们寻求其他替代能源。目前的研究探索了Albizia分支的微波热解,以评估其生产各种形式燃料(固体,液体,气体)的潜力,节省时间和有效的热传热。研究了关键参数对生物燃料生产数量和质量的影响,包括时间、功率水平、生物质重量和颗粒大小。结果表明,在功率为450 W、生物量为20 g的条件下,生物油的最佳产量为76%。此外,低功率水平导致生物炭产量增加,当采用300 W功率水平时,生物炭产量增加了70%。在所有情况下,使用更高的功率水平来增加气体燃料的产生,例如在700 W时,气体产量为31%。采用密度、粘度、酸度、HHV、GC-MS、FTIR等仪器分析了生物油的理化特性。GC-MS分析表明,生物油主要由芳香族化合物、酮类、醛类、酸类、酯类、烷烃、烯烃和杂环化合物组成。以芳香族化合物和酮类化合物居多,分别占12.79%和12.15%,所得油脂pH为5,HHV为19.5 MJ/kg。热解产物经进一步处理后可作为有前景的不同用途的原料。
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