Reduction of Heavy Metal (Pb) ions in industrial waste using activated carbon based on used catalysts

Netty Herawati, Rifdah, Ummi Kalsum, Nyayu Miftakhul Muthiah
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Abstract

Used catalyst-based activated carbon is activated carbon made from used catalysts from the crude oil cracking process. The used catalyst used is a type of crystalline Zeolite with a regular structure, which contains elements of Silica Oxide, Alumina Oxide, and Calcium Oxide. The use of organic activated carbon to treat waste has been widely used, the use of used catalyst waste as activated carbon is very potential because the catalyst used for oil company cracking is no longer used. Tofu industry is one of Indonesia's industries dominated by small-scale businesses with limited capital, so most tofu industries do not have waste treatment units, where liquid waste is directly discharged into sewers or water bodies without treatment first. Tofu industrial waste contains pollutants both organic and inorganic. Initial analysis of tofu industry liquid waste containing Pb metal. This study aims to determine the effect of mass variation and stirring time of used catalyst-based activated carbon adsorbent on reducing Heavy Metal Ions (Pb) in tofu industry liquid waste. The adsorption process is carried out with mass variations of activated carbon of 5, 10, 15, 20, and 25 grams. Stirring time variations are 30, 60, 90, 120, and 150 minutes. From the results of the study, it is known that the best condition for reducing Pb content was obtained at a stirring time of 60 minutes and a large catalyst-based activated carbon mass of 66.33%
基于废旧催化剂的活性炭还原工业废水中的重金属离子
废催化剂基活性炭是利用原油裂化过程中的废催化剂制成的活性炭。所使用的催化剂是一种具有规则结构的晶体沸石,它含有氧化硅、氧化氧化铝和氧化钙元素。利用有机活性炭处理废弃物已得到广泛应用,由于石油公司裂化所用的催化剂已不再使用,利用废旧催化剂废弃物作为活性炭具有很大的潜力。豆腐产业是印尼以小规模企业为主的产业之一,资金有限,所以大多数豆腐产业没有废物处理装置,废液不经处理直接排入下水道或水体。豆腐工业废料含有有机和无机污染物。豆腐工业废液含铅初步分析。研究了催化剂型活性炭吸附剂的质量变化和搅拌时间对豆腐工业废液中重金属离子(Pb)还原的影响。吸附过程以5、10、15、20和25克的活性炭质量变化进行。搅拌时间变化为30、60、90、120和150分钟。从研究结果可知,降低Pb含量的最佳条件为搅拌时间为60 min,催化剂基活性炭质量为66.33%
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