Eclogite thermobarometry: The consistency between conventional thermobarometry and forward phase-equilibrium modelling

Abstract

Eclogite thermobarometry is crucial for constraining the depths and temperatures to which oceanic and continental crust subduct. However, obtaining the pressure and temperature (P–T) conditions of eclogites is complex as they commonly display high-variance mineral assemblages, and the mineral compositions only vary slightly with P–T. In this contribution, we present a comparison between two independent and commonly used thermobarometric approaches for eclogites: conventional thermobarometry and forward phase-equilibrium modelling. We assess how consistent the thermobarometric calculations are using the garnet–clinopyroxene–phengite barometer and garnet–clinopyroxene thermometer with predictions from forward modelling (i.e. comparing the relative differences between approaches). Our results show that the overall mismatch in methods is typically ±0.2–0.3 GPa and ±29–42°C although differences as large as 80°C and 0.7 GPa are possible for a few narrow ranges of P–T conditions in the forward models. Such mismatch is interpreted as the relative differences among methods, and not as absolute uncertainties or accuracies for either method. For most of the investigated P–T conditions, the relatively minor differences between methods means that the choice in thermobarometric method itself is less important for geological interpretation than careful sample characterization and petrographic interpretation for deriving P–T from eclogites. Although thermobarometry is known to be sensitive to the assumed X_Fe³⁺ of a rock (or mineral), the relative differences between methods are not particularly sensitive to the choice of bulk-rock X_Fe³⁺, except at high temperatures (>650°C, amphibole absent) and for very large differences in assumed X_Fe³⁺ (0–0.5). We find that the most important difference between approaches is the activity–composition (a–x) relations, as opposed to the end-member thermodynamic data or other aspects of experimental calibration. When equivalent a–x relations are used in the conventional barometer, P calculations are nearly identical to phase-equilibrium models (ΔP < 0.1). To further assess the implications of these results for real rocks, we also evaluate common mathematical optimizations of reaction constants used for obtaining the maximum P–T with conventional thermobarometric approaches (e.g. using the highest aGrs² × aPrp in garnet and Si content in phengite, and the lowest aDi in clinopyroxene). These approaches should be used with caution, because they may not represent the compositions of equilibrium mineral assemblages at eclogite facies conditions and therefore systematically bias P–T calculations. Assuming method accuracy, geological meaningful P_max at a typical eclogite facies temperature of ~660°C will be obtained by using the greatest aDi, aCel, and aPrp and lowest aGrs and aMs; garnet and clinopyroxene with the lowest Fe²⁺/Mg ratios may yield geological meaningful T_max at a typical eclogite facies pressure of 2.5 GPa.