Evaluating the role of operating temperature and residence time in the torrefaction of betel nutshells for solid fuel production

Pongpathai Kitrungloadjanaporn, Le Quang Sang, Jirasak Pukdum, Tinnapob Phengpom
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Abstract

This research addresses the urgent need for sustainable bioenergy alternatives, specifically evaluating betel nutshells as potential replacements for conventional biomass materials like coconut and palm fibers. The objective of the study was to gauge the inherent bioenergy potential of betel nutshells through an investigation of torrefaction under varying conditions, specifically temperatures ranging from 200-300 °C and residence times between 20-60 minutes in an inert environment. In this study, proximate analyses were utilized to investigate essential characteristics including moisture content, volatile matter, ash content, and fixed carbon, while a bomb calorimeter was used to determine their higher heating values. Initial results indicated that untreated betel nutshells had higher heating values and compositional similarities to coconut and palm fibers, highlighting their potential as a bioenergy source. Advanced torrefaction processes, involving increased temperatures and extended residence times, raised the fixed carbon content and reduced moisture in betel nutshells, thereby optimizing their higher heating value. This improvement is attributed to the decomposition of covalent bonds in the biomass structures, leading to the release of volatile compounds and consequent reductions in both oxygen-to-carbon and hydrogen-to-carbon ratios. Remarkably, at an operating temperature of 300 °C and a residence time of 60 minutes, torrefied betel nutshells reached a higher heating value of 25.20 MJ/kg, marking a substantial 31.39 % increase compared to untreated specimens. This study conclusively positions betel nutshells, typically considered agricultural waste, as competitive alternatives to traditional biomass resources in the biofuel industry.
评价操作温度和停留时间对生产固体燃料用槟榔壳的烘烤作用
这项研究解决了对可持续生物能源替代品的迫切需求,特别是评估了槟榔壳作为椰子和棕榈纤维等传统生物质材料的潜在替代品。该研究的目的是通过在不同条件下(特别是在200-300°C的温度范围内和在惰性环境中停留20-60分钟之间)的烘烤调查来衡量槟榔壳的内在生物能源潜力。在本研究中,使用近似分析来研究基本特征,包括水分含量、挥发物、灰分含量和固定碳,同时使用炸弹量热计来确定其较高的热值。初步结果表明,未经处理的槟榔壳具有更高的热值,其成分与椰子和棕榈纤维相似,突出了其作为生物能源的潜力。先进的烘焙工艺,包括提高温度和延长停留时间,提高了槟榔壳的固定碳含量,降低了水分,从而优化了槟榔壳的高热值。这种改善归因于生物质结构中共价键的分解,导致挥发性化合物的释放,从而降低氧碳比和氢碳比。值得注意的是,在300°C的工作温度和60分钟的停留时间下,固化槟榔壳的热值达到了25.20 MJ/kg,比未处理的样品提高了31.39%。这项研究最终将槟榔壳(通常被认为是农业废物)定位为生物燃料工业中传统生物质资源的竞争性替代品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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