Iron(III) complexes with ditopic macrocycles bearing crown-ether and bis(salicylidene) isothiosemicarbazide moieties

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI:10.2298/jsc230607065a

Vladimir Arion, Oleg Palamarciuc, Sergiu Shova, Ghenadie Novitchi, Peter Rapta

引用次数: 0

Abstract

The main aims of this work were the synthesis and characterization of iron(III) complexes with with a ditopic ligand H2L consisting of a bis(salicylidene)isothiosemicarbazide moiety with a N2O2 binding site and a crown-ether (O6) moiety. A series of high-spin iron(III) complexes, i.e. [FeIIILClBa(CH3OH)(H2O)0.5(ZnCl4)] (1), [FeIIILCl] (2), [FeIIIL(N3)] (3) and [(FeIIIL)2O] (4), were synthesized. The complexes were characterized by mass spectrometry, IR and UV-vis spectroscopy, variable temperature (VT) magnetic susceptibility measurements, M?ssbauer spectroscopy, single crystal X-ray diffraction and cyclic voltammetry.

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含冠醚和双(水杨基)异硫代氨基脲的双位大环铁配合物

本工作的主要目的是合成和表征铁(III)配合物与双位配体H2L，该配体由具有N2O2结合位点的双(水杨基)异硫代氨基脲和冠醚(O6)部分组成。合成了一系列高自旋铁(III)配合物[FeIIILClBa(CH3OH)(H2O)0.5(ZnCl4)](1)、[FeIIILCl](2)、[feiiiln3)](3)和[(feiiil2o)](4)。采用质谱、红外光谱、紫外-可见光谱、变温磁化率、M?斯堡尔光谱，单晶x射线衍射和循环伏安法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of The Serbian Chemical Society 化学-化学综合

CiteScore

1.80

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of the Serbian Chemical Society -JSCS (formerly Glasnik Hemijskog društva Beograd) publishes articles original papers that have not been published previously, from the fields of fundamental and applied chemistry: Theoretical Chemistry, Organic Chemistry, Biochemistry and Biotechnology, Food Chemistry, Technology and Engineering, Inorganic Chemistry, Polymers, Analytical Chemistry, Physical Chemistry, Spectroscopy, Electrochemistry, Thermodynamics, Chemical Engineering, Textile Engineering, Materials, Ceramics, Metallurgy, Geochemistry, Environmental Chemistry, History of and Education in Chemistry.