None Sana Ibadat, None Hafiza Tauseef Ashfaq, None Ruqia, None Muhammad Adeel Asghar, None Ali Haider, None Saqib Ali
{"title":"Surfactant-Promoted Prussian Blue Analogues Fabricated Electrodes for Electrocatalytic Water Oxidation","authors":"None Sana Ibadat, None Hafiza Tauseef Ashfaq, None Ruqia, None Muhammad Adeel Asghar, None Ali Haider, None Saqib Ali","doi":"10.53560/ppasb(60-3)834","DOIUrl":null,"url":null,"abstract":"Prussian blue analogues (PBAs) have unique structural and chemical behaviour and therefore have applications in various fields of catalysis as energy conversion materials for storage devices and molecular sensing. Herein we focused on the in-situ synthesis of three PBAs comprising cobalt hexacyanoferrate (CoHCF), nicke<l hexacyanoferrate (NiHCF), and cobalt-nickel hexacyanoferrate (CoNiHCF) through cation i.e. cetyltrimethylammonium bromide (CTAB) assisted drop cast method. The electrocatalysts were characterized through a multitude of spectroscopic techniques and were tested for water oxidation study. It was found that among the three electrocatalysts, CoNiHCF showed comparatively better catalytic performance with an overpotential value of 570 mV (at 1 mA cm-2).","PeriodicalId":36960,"journal":{"name":"Proceedings of the Pakistan Academy of Sciences: Part B","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the Pakistan Academy of Sciences: Part B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.53560/ppasb(60-3)834","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Agricultural and Biological Sciences","Score":null,"Total":0}
引用次数: 0
Abstract
Prussian blue analogues (PBAs) have unique structural and chemical behaviour and therefore have applications in various fields of catalysis as energy conversion materials for storage devices and molecular sensing. Herein we focused on the in-situ synthesis of three PBAs comprising cobalt hexacyanoferrate (CoHCF), nicke
普鲁士蓝类似物(PBAs)具有独特的结构和化学行为,因此作为存储装置和分子传感的能量转换材料在催化的各个领域都有应用。本文主要研究了原位合成六氰高铁酸钴(CoHCF)、六氰高铁酸镍(NiHCF)和六氰高铁酸钴镍(CoNiHCF)三种多环芳烃的方法,即十六烷基三甲基溴化铵(CTAB)辅助滴铸法。通过多种光谱技术对电催化剂进行了表征,并进行了水氧化研究。结果表明,在三种电催化剂中,CoNiHCF表现出较好的催化性能,过电位值为570 mV (1 mA cm-2)。