Recent Advances in Electrochemical Reductive Transformation of C−C and C−O Multiple Bonds

IF 2.3 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Israel Journal of Chemistry Pub Date : 2023-11-08 DOI:10.1002/ijch.202300102

Atreyee Halder, Kingshuk Mahanty, Debabrata Maiti, Dr. Suman De Sarkar

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引用次数: 0

Abstract

In recent decades, electro-organic synthesis is indubitably emerging as a cornerstone of modern organic chemistry. Electrochemical organic transformations especially reduction reactions have made massive advancements in the last few years because of their sustainable and environ-friendly nature. Electro-reductive protocols can be used as a promising substitute for conventional reductants by expelling the requirement of the stoichiometric amount of metal reductants. The major challenges for these electro-reductive reactions are primarily the use of a sacrificial electrode and divided cells. These limitations can be resolved through smart reaction planning by employing cheap sacrificial reagents or paired electrolysis without compromising the sustainable viewpoint. Considering the rapid enhancement in this field, imparting an intangible understanding of this evolving area is essential and substantial. In this review, we portrayed the electrochemical reductive transformations of C−C and C−O bonds after 2015 along with detailed mechanistic insights.

Abstract Image

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C-C 和 C-O 多键电化学还原转化的最新进展

近几十年来，电有机合成已无可争议地成为现代有机化学的基石。电化学有机转化，尤其是还原反应，因其可持续和环保的特性，在过去几年中取得了巨大的进步。电还原反应不需要等量的金属还原剂，因此可以替代传统的还原剂。这些电还原反应面临的主要挑战是使用牺牲电极和分隔电池。这些限制可以通过采用廉价的牺牲试剂或配对电解进行智能反应规划来解决，而不会影响可持续观点。考虑到这一领域的快速发展，传授对这一不断发展的领域的无形理解至关重要。在这篇综述中，我们描绘了 2015 年之后 C-C 和 C-O 键的电化学还原转化以及详细的机理见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Israel Journal of Chemistry 化学-化学综合

CiteScore

6.20

自引率

0.00%

发文量

审稿时长

6-12 weeks

期刊介绍： The fledgling State of Israel began to publish its scientific activity in 1951 under the general heading of Bulletin of the Research Council of Israel, which quickly split into sections to accommodate various fields in the growing academic community. In 1963, the Bulletin ceased publication and independent journals were born, with Section A becoming the new Israel Journal of Chemistry. The Israel Journal of Chemistry is the official journal of the Israel Chemical Society. Effective from Volume 50 (2010) it is published by Wiley-VCH. The Israel Journal of Chemistry is an international and peer-reviewed publication forum for Special Issues on timely research topics in all fields of chemistry: from biochemistry through organic and inorganic chemistry to polymer, physical and theoretical chemistry, including all interdisciplinary topics. Each topical issue is edited by one or several Guest Editors and primarily contains invited Review articles. Communications and Full Papers may be published occasionally, if they fit with the quality standards of the journal. The publication language is English and the journal is published twelve times a year.