Mn<sup>4+</sup>-doped Red-emitting Fluoride Phosphors with Intense Zero Phonon Line

发光学报 Pub Date : 2023-01-01 DOI:10.37188/cjl.20230107
Wenrui ZHANG, Lulu HE, Zhaowu WANG, Haipeng JI
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引用次数: 0

Abstract

Mn4+æ¿€æ´»è§å ‰ç²‰å®žçŽ°å¼ºé›¶å£°å­çº¿ï¼ˆZero phonon line,ZPLï¼‰å‘å ‰å°†ä¼šä½¿å ¶å‘å°„å ‰è°±ä¸­çŸ­æ³¢çº¢å ‰å¢žå¼ºï¼Œä¸”å¸¸ä¼´éšè§å ‰å¯¿å‘½ç¼©çŸ­ã€‚æœ¬æ–‡å¯¹Mn4+æ¿€æ´»æ°ŸåŒ–ç‰©çº¢å ‰è§å ‰ç²‰ä¸­å ·æœ‰å¼ºZPLå‘å ‰ç‰¹å¾çš„28ç§è§å ‰ç²‰çš„ç»„æˆã€åˆ¶å¤‡ã€æ™¶ä½“ç»“æž„ä¸Žè§å ‰æ€§è´¨è¿›è¡Œç»¼è¿°ã€‚å‘çŽ°äº†ä¸€äº›è§„å¾‹ï¼šï¼ˆ1)这28ç§è§å ‰ç²‰å¯ä»¥æ ¹æ®Mn4+ä¸Žè¢«å–ä»£ç¦»å­æ˜¯å¦ä¸ºç­‰ä»·å–ä»£åŠè¢«å–ä»£ç¦»å­åœ¨åŸºè´¨ä¸­æ˜¯å¦å½¢æˆå ­é ä½åˆ†ä¸ºå››ç±»ã€‚ï¼ˆ2)[MnF6ï¼½é ä½å «é¢ä½“ç•¸å˜æ˜¯Mn4+实现强ZPLå‘å ‰çš„å¿ è¦æ¡ä»¶ã€‚ï¼ˆ3)大部分Mn4+激活强ZPLæ°ŸåŒ–ç‰©è§å ‰ç²‰ä¸­Mn4+掺杂为对3+ç¦»å­çš„ä¸ç­‰ä»·å–ä»£ï¼›åœ¨ç­‰ä»·å–ä»£ä¸”è¢«å–ä»£ç¦»å­ä¸ºå ­é ä½æ—¶ï¼ŒèŽ·å¾—å¼ºZPL发射的空间群主要为P321和P3m1等三方晶系空间群。(4)Mn4+在绝大多数强ZPLå‘å°„æ°ŸåŒ–ç‰©è§å ‰ç²‰ä¸­ZPL都弱于ν6å£°å­ä¼´å³°ï¼Œä» åœ¨Na2TiF6∶Mn4+等5ç§è§å ‰ç²‰ä¸­ZPL强于ν6峰。(5ï¼‰å ¶ZPL波长都在617~628 nm之间,多数为620 nm。(6)ZPL与Stokes ν6å³°çš„å¼ºåº¦æ¯”ä¸ä» ä¸Žè§å ‰ç²‰çš„åŒ–å­¦ç»„æˆæœ‰å ³ï¼›å¯¹äºŽåŒä¸€åŒ–å­¦ç»„æˆçš„è§å ‰ç²‰ï¼Œè¯¥æ¯”å€¼ä¹Ÿéšåˆ¶å¤‡æ–¹æ³•çš„æ”¹å˜è€Œå˜åŒ–ã€‚
Mn<sup>4+</sup>-掺杂具有强零声子线的红发氟化物荧光粉
Mn4+æ¿æ´"觧å ç²å®ç°å¼ºé¶å£°å线ï¼ZPLï¼¼å å°ä¼ä½¿å ¶å°å è°±ä¸ç¢çº¢å å¢å¼ºï¼ä¸¸ä¼´é§å1:28:00-2:30:00,在 "Mn4+"选项中选择"-",在"-"选项中选择""。MnF6+Mn4+ZPL+Mn3+Mn4+ZPLNa2TiF6+Mn4+5(ZPL)(617~628)(620)(620)我是一个很有创意的人。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
发光学报
发光学报 Physics and Astronomy-Radiation
CiteScore
1.90
自引率
0.00%
发文量
7477
期刊介绍: Chinese Journal of Luminescence (CJL), supervised by Chinese Academy of Sciences (CAS), Sponsored by Committee on luminescence of Chinese Physical Society and Changchun Institute of Optics, Fine mechanics and Physics(CIOMP)of Chinese Academy of Sciences, is an authoritatively scientific and technical periodical of China in the field of luminescence, which is read widely in providing original papers and reviews that describe recent developments on basic theory and experimental studies of excited state processes and green lighting projects. The journal was established at 1980, and named after LUMINESCENCE AND DISPLAY, then renamed as CJL in 1986.
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