Modelling of Electrochemical Processes and Joulemetric Measuring Systems

Abstract

The paper considers the issues of modelling electrochemical processes while developing methods and means of controlling the dynamics of inflammatory processes in the joulemetric measuring systems, and presents the peculiarities of controlling biological objects and the basic regularities of electrochemical cells functioning. The principle of the operation of electrochemical cells underlies the joulemetric method. Proteins and nucleic acids are information macromolecules. Covalent, ionic, ion-dipole, and dispersion bonds between them give biological objects electrochemical properties. Electrochemical investigations can be most effectively carried out with the use of contact sensors with ion selective membranes. Their use makes it possible to obtain electrical parameters and to study the Faraday processes taking place in biological objects. The main model is an electrochemical cell, which is considered from the perspective of thermodynamics and diffusion of electrically charged particles. In the end, one obtains the equations that allow to connect the thermodynamic and statistical description of phenomena in the electrochemical cell, to draw a conclusion on the relationship between the substance reaction rate in the electrochemical cell and the current density for this substance, and to construct a closed mathematical model of physical and chemical processes inside the electrochemical cell in order to develop and justify electrochemical methods and means of controlling the dynamics of inflammatory processes.