SYNTHESIS OF HIGHLY EFFICIENT SORBENTS FROM PLANT WASTE

E. Elnaggar
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Abstract

The possibility of creating a wide range of carbon adsorbents is greatly facilitated by the variety of the initial carbon-containing raw materials and technologies for its processing. At present, the main raw materials for the industrial production of adsorbents are wood, fossil coal, peat, remnants of processing of agricultural raw materials, and some polymeric materials. Lignin and carbon black (soot) are used much less frequently. However, potentially carbon adsorbents can be obtained from a much wider range of solid, liquid and gaseous carbonaceous substances, many of which are currently considered only useless domestic and industrial waste. Thus, adsorbents with satisfactory characteristics, active in specific technological processes, can be synthesized from waste wood and bark, lignin and the pulp and paper industry, activated sludge, associated gases, etc. On the basis of it was received by the sorbent capable to catch oil. Its capacity is 1–2 g/g, but the cleaning efficiency can reach 90 %. The black ash walnut shell has excellent absorption properties and is not inferior in quality to the best brands of activated carbon. Surface treatment of water or wastewater proposed sorbent was carried out at 0–100 °C. Regeneration of used sorbent spend its processing hydrocarbon solvents (gasoline, kerosene, etc.) or organic solvents (alcohols, etc.) or mixtures thereof.
利用植物废弃物合成高效吸附剂
最初的含碳原料和加工技术的多样性大大促进了制造各种碳吸附剂的可能性。目前工业生产吸附剂的主要原料有木材、化石煤、泥炭、农业原料加工后的残余物,以及一些高分子材料。木质素和炭黑(烟灰)的使用频率要低得多。然而,潜在的碳吸附剂可以从更广泛的固体、液体和气体碳质物质中获得,其中许多目前被认为只是无用的家庭和工业废物。因此,可以从废木材和树皮、木质素、纸浆和造纸工业、活性污泥、伴生气体等中合成具有满意特性、在特定工艺过程中具有活性的吸附剂。在此基础上得到了能吸附油污的吸附剂。其容量为1-2克/克,但清洗效率可达90%。黑灰核桃壳具有优异的吸收性能,质量不逊于最好品牌的活性炭。采用吸附剂对水或废水进行表面处理,温度为0-100℃。再生用过的吸附剂,其处理的烃类溶剂(汽油、煤油等)或有机溶剂(醇类等)或其混合物。
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