The mechanism of Al contents (0–0.09 wt%) on the wettability and interfacial intermetallic compounds growth of Zn-25Sn/Cu

Kwang-Lung Lin, Xiaodong Niu
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Abstract

The wettability of the solders Zn-25Sn-XAl (x=0–0.09wt%) was investigated by dipping method. The interfaces between solders and Cu substrate were investigated by scanning electron microscopy (SEM), electron probe microanalysis (EPMA) and energy dispersive spectroscopy (EDS) equipped in transmission elctron microscopy (TEM). It was found that the addtion of Al enhances the wettability of the solders on Cu. The three layers (Cu,Al)Zn, (Cu,Al)5Zn8 and (Cu,Al)Zn5 were found at the interfaces between Cu substrate and solders. The thickness of intermetallic compounds layers increased with Al additions. The higher Al addition, the higher Al intetnsity was detected in the intermetallic compounds layer. The Al addition exhibits two stages behaivor on both wetting time and interfacial intermetallic growth.
Al含量(0 ~ 0.09 wt%)对Zn-25Sn/Cu合金润湿性和界面金属间化合物生长的影响机理
采用浸渍法研究了焊料Zn-25Sn-XAl (x=0 ~ 0.09wt%)的润湿性。采用扫描电镜(SEM)、电子探针微分析(EPMA)和透射电镜(TEM)能谱仪(EDS)对钎料与Cu衬底之间的界面进行了研究。结果表明,Al的加入提高了钎料在Cu表面的润湿性。在Cu衬底与钎料界面处形成(Cu,Al)Zn、(Cu,Al)5Zn8和(Cu,Al)Zn5三层。Al的加入增加了金属间化合物层的厚度。Al加入量越高,金属间化合物层的Al强度越高。Al的加入在润湿时间和界面金属间生长上均表现为两阶段行为。
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