Faster Curing Ethylene-Silane Copolymer for Wire and Cable Applications

B. I. Chaudhary, Kurt Bolz, Peter Dreux
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Abstract

A “faster curing” ethylene-silane copolymer has been designed as an alternative to existing ethylene-silane copolymers or silane grafted polyethylenes. Rapid crosslinking at ambient conditions has been demonstrated with the “faster curing” co-polymer. Even with its enhanced cure characteristics, the “faster curing” co-polymer still exhibits excellent processability during melt extrusion. For applications where blends with non-silane functionalized polymers are desirable (or required), dilution with up to 50% LLDPE has been demonstrated while maintaining acceptable cure rate and extent of crosslinking, and even greater dilution is possible. The “faster curing” copolymer also maintains superior shelf-life stability over Sioplas silane grafted polyethylene. The “faster curing” copolymer is also a suitable alternative to Monosil silane grafted polyethylene and can be provided for use in bulk in addition to traditional boxes and bags.
用于电线电缆应用的更快固化乙烯-硅烷共聚物
一种“更快固化”的乙烯-硅烷共聚物被设计为现有的乙烯-硅烷共聚物或硅烷接枝聚乙烯的替代品。在环境条件下快速交联已被证明与“更快固化”的共聚物。即使具有增强的固化特性,“快速固化”共聚物在熔融挤出过程中仍然表现出优异的加工性。对于希望(或需要)与非硅烷功能化聚合物共混的应用,在保持可接受的固化速率和交联程度的同时,已证明稀释度高达50%的LLDPE,甚至更大的稀释是可能的。与Sioplas硅烷接枝聚乙烯相比,“更快固化”的共聚物也保持了更好的保质期稳定性。“快速固化”共聚物也是monsil硅烷接枝聚乙烯的合适替代品,除了传统的盒子和袋子外,还可以提供散装使用。
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