A Comparison Between Local and Global Models Among Different Near Infrared Spectroscopy Instruments for Corn Oils Prediction

Xien Yin Yap, K. Chia
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Abstract

Near infrared (NIR) sensing technology has been widely implemented in various areas due to its noninvasive, green, and rapid measurement features. Artificial Neural Network (ANN) was used for the NIR calibration model. ANN can provide a reliable local calibration model using local data. However, a reliable local calibration model could be invalid or degraded when it is directly used for other instruments. This is because the instrumental variation causes the Local model's performance invalid. The instrumental variation is the difference among the spectra acquired by different instruments. The Global model identified the instrumental variation due to the Global model was developed with the calibration dataset acquired from two or more instruments. Thus, this study aims to compare the Local and Global models' performance among different NIR spectroscopy instruments in corn oil prediction. First, principle component analysis (PCA) was used to compress the NIR spectra. After that, Bayesian (BR) learning algorithm was applied to train an ANN with different initial conditions and hidden neurons to identify an optimal ANN for the primary instrument. The procedure of Global model development was similar to the Local model. The difference between Local and Global models is the global model used two or more calibration datasets to develop the model. Findings show that Global model was the best with the lowest root mean square error of prediction (RMSEP) of 0.1630%, followed by Local model of 0.4074% and 0.4330% for mp5 and mp6 as calibration datasets, respectively and the best correlation coefficient of 0.7514, 0.6532, and 0.7297, respectively, tested with m5 testing dataset in corn oils prediction applications. The same performance was found when the testing dataset were mp5 and mp6.
不同近红外仪器对玉米油局部和全局预测模式的比较
近红外(NIR)传感技术以其无创、绿色、快速等特点在各个领域得到了广泛的应用。采用人工神经网络(ANN)进行近红外标定模型。人工神经网络可以利用局部数据提供可靠的局部标定模型。然而,当直接用于其他仪器时,可靠的局部校准模型可能无效或降级。这是因为仪器变化导致局部模型的性能失效。仪器差异是指不同仪器获得的光谱之间的差异。由于Global模式是利用从两个或多个仪器获得的校准数据集开发的,因此Global模式确定了仪器变化。因此,本研究旨在比较不同近红外光谱仪器中局部模型和全局模型在玉米油预测中的性能。首先,利用主成分分析(PCA)对近红外光谱进行压缩。然后,利用贝叶斯学习算法训练具有不同初始条件和隐藏神经元的人工神经网络,为主仪器识别最优的人工神经网络。全局模型的开发过程与局部模型相似。局部模式与全局模式的区别在于全局模式使用两个或多个校准数据集来开发模型。结果表明,mp5和mp6作为校正数据集,Global模型的预测均方根误差(RMSEP)最低,为0.1630%;Local模型次之,分别为0.4074%和0.4330%;m5测试数据集的相关系数最高,分别为0.7514、0.6532和0.7297。当测试数据集为mp5和mp6时,发现了相同的性能。
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