Features of the Ionic State of Indium in Perchlorate Solutions and the Physicochemical Properties of Indium Perchlorate

Radionov Boris Konstantinovich, Svirsky Ilya Anatolievich
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Abstract

The possibility of the formation of India perchlorate and mixed ligand complexes has been studied. It is assumed that during the extraction of indium in aqueous solutions of hydrochloric acid at various concentrations and constant ionic strength maintained by the addition of perchloric acid, indium is present in the organic phase in the form of ionic aggregates HClO4 · HInCl4. To study the hydration of Ions, the method of electrical conductivity was carried out in the “In(ClO4)3 - HClO4 - H2O” system. The structure of aqueous solutions of India perchlorates was determined by IR spectroscopy. The structures of trivalent perchlorate India have been established.
高氯酸盐溶液中铟离子态的特征及高氯酸铟的理化性质
研究了高氯酸盐与混合配体络合物形成的可能性。假设在不同浓度的盐酸水溶液中,在高氯酸保持一定离子强度的条件下,铟在有机相中以离子聚集体HClO4·HInCl4的形式存在。为了研究离子的水化作用,在“in (ClO4)3 - HClO4 - H2O”体系中进行了电导率法。用红外光谱法测定了印度高氯酸盐水溶液的结构。已经确定了三价高氯酸盐的结构。
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