Comparison between Lewis and Crine models for the electrical aging of dielectric polymers

J. Crine
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引用次数: 8

Abstract

The electrical aging model of Lewis is compared with the modified version of Crine model. Both rely on thermodynamic and both associate the onset of aging with submicrocavity formation. The major differences in the two models are discussed in light of electrical aging data for XLPE cables. Although both models give a good fit to experimental data, Lewis model involves much more parameters and some of them are not readily accessible. On the other hand, Crine revised model depends on the cohesion energy of the polymer, on the activation energy and on the volume activation of the process. The physical significance of these parameters for the accelerated aging of polymers (especially those used in extruded cables) is also discussed.
介电聚合物电老化的Lewis和Crine模型比较
将Lewis的电老化模型与修正后的Crine模型进行了比较。两者都依赖于热力学,两者都将老化的开始与亚微腔的形成联系起来。结合交联聚乙烯电缆的电老化数据,讨论了两种模型的主要区别。虽然两种模型都能很好地拟合实验数据,但刘易斯模型涉及的参数更多,其中一些参数不易获取。另一方面,Crine修正模型取决于聚合物的内聚能、活化能和过程的体积活化能。本文还讨论了这些参数对聚合物(特别是用于挤压电缆的聚合物)加速老化的物理意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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