V. Jain, A. Baraskar, M. Wistey, U. Singisetti, Z. Griffith, E. Lobisser, B. Thibeault, A. Gossard, M. Rodwell
{"title":"Effect of surface preparations on contact resistivity of TiW to highly doped n-InGaAs","authors":"V. Jain, A. Baraskar, M. Wistey, U. Singisetti, Z. Griffith, E. Lobisser, B. Thibeault, A. Gossard, M. Rodwell","doi":"10.1109/ICIPRM.2009.5012438","DOIUrl":null,"url":null,"abstract":"We report the effects of UV-ozone oxidation, oxide removal etch chemistry (dilute HCl or concentrated NH<inf>4</inf>OH), semiconductor doping, and annealing on the contact resistivity (ρ<inf>c</inf>) of Ti<inf>0.1</inf>W<inf>0.9</inf> refractory alloy to n-type InGaAs. The semiconductor surface was oxidized through exposure to UV-ozone, then subsequently etched by either dilute HCl or concentrated NH<inf>4</inf>OH before TiW contacts were deposited by blanket sputtering. InGaAs samples doped at 5 × 10<sup>19</sup> cm<sup>−3</sup>, treated with 10 minutes of UV-Ozone then one minute dilute HCl exhibited ρ<inf>c</inf> of (1.90 ± 0.35) × 10<sup>−8</sup> Ω-cm<sup>2</sup>. The contacts are thermally stable at least to 400 °C where after one minute anneal, ρ<inf>c</inf> reduced to (1.29 ± 0.28) × 10<sup>−8</sup> Ω-cm<sup>2</sup>. TiW contacts on samples having same active dopants, with no UV-ozone oxidation and only 10 seconds of concentrated NH<inf>4</inf>OH etch exhibit ρ<inf>c</inf> of (2.49 ± 0.40) ± 10<sup>−8</sup> Ω-cm<sup>2</sup>.","PeriodicalId":119124,"journal":{"name":"2009 IEEE International Conference on Indium Phosphide & Related Materials","volume":"88 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2009-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"2009 IEEE International Conference on Indium Phosphide & Related Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICIPRM.2009.5012438","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 9
Abstract
We report the effects of UV-ozone oxidation, oxide removal etch chemistry (dilute HCl or concentrated NH4OH), semiconductor doping, and annealing on the contact resistivity (ρc) of Ti0.1W0.9 refractory alloy to n-type InGaAs. The semiconductor surface was oxidized through exposure to UV-ozone, then subsequently etched by either dilute HCl or concentrated NH4OH before TiW contacts were deposited by blanket sputtering. InGaAs samples doped at 5 × 1019 cm−3, treated with 10 minutes of UV-Ozone then one minute dilute HCl exhibited ρc of (1.90 ± 0.35) × 10−8 Ω-cm2. The contacts are thermally stable at least to 400 °C where after one minute anneal, ρc reduced to (1.29 ± 0.28) × 10−8 Ω-cm2. TiW contacts on samples having same active dopants, with no UV-ozone oxidation and only 10 seconds of concentrated NH4OH etch exhibit ρc of (2.49 ± 0.40) ± 10−8 Ω-cm2.