Feasibility of Water Hyacinth Ash as an Accelerator in Cement Slurry Formulation

Neminebor Gift, Adewole Steve, Akpoturi Peters
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Abstract

Cement is primarily used in drilling operations to protect the casing against the corrosive tendency of formation fluid and to support the casing with the external load on and around it. Cement slurry is formed by mixing water with Portland cement or with cement containing various essential additives as the case may be and pumping it down through to critical points in the annulus around the casing using various techniques. Class G cement is widely used in cementing jobs because it allows the use of accelerators and retarders for wide range of well depths and temperatures. Due to wait-on-cement time before commencement of drilling of the next section of the well, it is necessary to reduce the waiting time and it ripple effects on cost of drilling by introducing accelerator to the cement slurry. The chlorides of calcium, potassium and sodium are the commonly used accelerators. Water hyacinth ash have been known to contain high percentage of calcium, potassium and chlorine, these elements readily combine with water to form potassium chloride and calcium chloride of which both are used as accelerator additives in cement slurry formulation. The utilization of these compounds in water hyacinth ash as accelerator additives would be a major breakthrough in cementing jobs especially in shallow section of the wells. Locally sourced water hyacinth plants were dried and combusted in air, the ash was then activated with water and filtered. The filtrate was used to determine the thickening time of class G cement slurry and the results obtained was compared with that of inorganic calcium chloride. The thickening times at the various set temperatures for this experiment were close to the inorganic calcium chloride used. Though, the thickening time of cement slurry is dependent on temperature, the concentration of the accelerator in the slurry also affect it.. It was found out that water hyacinth ash reduces the thickening time of class G cement slurry comparatively and therefore, should be considered as accelerator additive in the formulation of oil well cement slurry for accelerating the cement setting time.
水葫芦灰在水泥浆配方中作促进剂的可行性
水泥主要用于钻井作业,以保护套管免受地层流体的腐蚀,并在外部载荷作用下支撑套管。水泥浆是通过将水与波特兰水泥或含有各种基本添加剂的水泥混合形成的,并使用各种技术将其泵入套管周围环空的关键点。G类水泥被广泛应用于固井作业,因为它允许在很宽的井深和温度范围内使用加速剂和缓凝剂。由于下一段井开始钻井前需要等待一段时间,因此有必要通过在水泥浆中引入促进剂来减少等待时间及其对钻井成本的连锁反应。钙、钾、钠的氯化物是常用的加速剂。众所周知,水葫芦灰含有高比例的钙、钾和氯,这些元素很容易与水结合形成氯化钾和氯化钙,这两种元素都被用作水泥浆配方中的促进剂添加剂。利用水葫芦灰中的这些化合物作为促进剂,将是固井作业特别是浅井段固井作业的重大突破。当地的水葫芦植物被晒干,在空气中燃烧,然后用水活化和过滤灰烬。用该滤液测定了G类水泥浆的稠化时间,并与无机氯化钙进行了比较。本实验在不同设定温度下的增稠时间接近于所使用的无机氯化钙。虽然水泥浆的稠化时间取决于温度,但水泥浆中促进剂的浓度也会影响水泥浆的稠化时间。研究发现水葫芦灰相对缩短了G类水泥浆的稠化时间,因此在油井水泥浆配方中应考虑作为促进剂,以加快水泥的凝结时间。
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