Surface conductance measurements of adsorbed gases

Abstract

The surface conductance of adsorbed water, carbon dioxide, and ammonia has been measured as a function of temperature using a triple-track test substrate. The individual pure gases were studied along with their mixtures. Adsorbed carbon dioxide or ammonia was found to have a negligible surface conductance, while adsorbed water exhibited an increase in conductance beginning at -25/spl deg/C. Mixtures of carbon dioxide and water exhibited essentially the same conductance as water by itself, while mixtures of ammonia and water exhibited a conductance 10/sup 4/ times larger than water between -40/spl deg/C and 0/spl deg/C. Mixtures of all three gases resulted in a relatively low conductance at lower temperatures (-100/spl deg/C to -50/spl deg/C). Corresponding pressure measurements indicated that vaporization was greatly suppressed in some cases, suggesting strong interaction between the adsorbed species.<>