New Methods in the Synthesis of (Meth)Acrylates

C. Soykan
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Abstract

Generally, the words “reactive polymers” and “functional polymers” mean the same thing and are used interchangeably in most studies and describe cross-linked (insoluble) bead-structured resins containing chemically reactive functional groups. In this way, reactive polymers are widely used as polymeric reagents or polymer supports in biochemical and chemical applications. Functional (meth) acrylates referred here to supply “functional esters” ruins as a general reactive group precursor. In other sense, the leaving (activating) groups of these monomers may easily react with the alcohols and amines carrying the desired reactive groups and therefore, in general, provide a single reaction step for the synthesis of reactive polymers. In this paper, we suggest new routes for a new (meth)acrylate-based monomers and polymers. Also, the synthesis of a serial new (meth)acrylate esters including amide, dioxolane, benzofuran, and chalcone groups is described.
合成(甲基)丙烯酸酯的新方法
一般来说,“反应性聚合物”和“功能聚合物”意思相同,在大多数研究中可以互换使用,描述含有化学反应性官能团的交联(不溶)珠状结构树脂。因此,反应性聚合物在生物化学和化学应用中广泛用作聚合试剂或聚合物载体。这里提到的功能(甲基)丙烯酸酯提供“功能酯”遗迹作为一般反应基团前体。换句话说,这些单体的离开(活化)基团可以很容易地与携带所需活性基团的醇和胺反应,因此,一般来说,为合成活性聚合物提供了一个单一的反应步骤。在本文中,我们提出了新的(甲基)丙烯酸酯基单体和聚合物的新路线。此外,还介绍了酰胺、二氧唑烷、苯并呋喃和查尔酮等一系列新型(甲基)丙烯酸酯的合成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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