Atomic Spectroscopy: Technique of Paramount Credence

J. Ramkumar
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Abstract

Analytical technique is can be defined as a means to verify the chemical or physical property of a matter. In actual practice, there are extensive assortment of techniques ranging from simple ones like sample weighing to sophisticated methods using highly dedicated instrumentation. The most primordial technique is the classical method like gravimetry (based on weight measurement), titrimetry (based on addition of a solution to sample solution). Spectrochemical methods are based on the measurement of spectrum of the samples using different instruments. Electroanalytical methods utilize the potential or current of a electrochemical cell for determination of sample concentration. Chromatography is a separation based technique used to isolate the analyte from the other species to enable interference free determination. 1 Spectrochemical methods depends on spectroscopy which is the study and measurement of the spectrum produced upon interaction of sample with electromagnetic (EM) radiation as function of frequency or wavelength of radiation. There are diverse forms of spectroscopy namely acoustic resonance (Cost effective spectroscopy technique in acoustic region, mainly ultrasonic & sonic regions), X-ray photoelectron (relies on diffraction patterns created while X-rays pass through crystalline materials), circular dichroism (helps in differentiating left & right circularly polarised light by sample), Ultraviolet-Visible (UV/Vis) Spectroscopy (probing the electronic structure for identification of compounds), NMR Spectroscopy (measure magnetic fields around nuclei using radio waves), Infrared Spectroscopy (IR region of EM radiation is used), Raman spectroscopy (for identification of molecules based on
原子光谱学:最可靠的技术
分析技术可以定义为一种验证物质的化学或物理性质的手段。在实际操作中,有各种各样的技术,从简单的样品称重到使用高度专用仪器的复杂方法。最原始的技术是经典的方法,如重力法(基于重量测量),滴定法(基于向样品溶液中添加溶液)。光谱化学方法是基于使用不同仪器测量样品的光谱。电分析方法利用电化学电池的电位或电流来测定样品浓度。色谱法是一种基于分离的技术,用于将分析物从其他物质中分离出来,以实现无干扰的测定。光谱化学方法依赖于光谱学,它是研究和测量样品与电磁辐射(EM)相互作用时产生的光谱作为辐射频率或波长的函数。光谱学有多种形式,即声共振(声学区域的成本效益光谱学技术,主要是超声波和声波区域),x射线光电子(依赖于x射线通过晶体材料时产生的衍射图案),圆二色性(有助于通过样品区分左右圆偏振光),紫外-可见(UV/Vis)光谱学(探测电子结构以识别化合物),核磁共振光谱学(利用无线电波测量原子核周围的磁场)、红外光谱学(利用红外区域的EM辐射)、拉曼光谱学(用于识别分子的基础)
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