Development Of The Fabrication Process Of Carbon Nanotube Reinforced Polylactide Acid Nanofiber And Evaluation Of Its Mechanical Properties

K. Tanaka, M. Hashimoto, M. Nagura, T. Katayama
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引用次数: 1

Abstract

Due to the high surface area to volume ratio, nanofibers are expected to be used for a wide range of applications such as tissue engineering, filter media and reinforcements in composites. The electrospinning technique is a simple method for the fabrication of nanofibers. In this technique, a polymer solution is blown out from a needle hole, while an electric field is applied between a polymer solution and a target. During the electrospinning process, the solvent evaporates and polymer nanofibers are fabricated on the target. To add special functions to nanofibers, functional particle such as calcium carbonate and TiO2 were reported to be used as nano-fillers for nanofibers. Carbon nanotube (CNT), which has excellent mechanical, electrical, chemical resistance and electromagnetic properties, was reported to be reinforcement for bulk polymer resin and CNT is anticipated to be a reinforcing nano-fillers. However, due to challenges such as manipulating extremely small fibers, preparing samples of single-nanofiber and sourcing for accurate and sensitive force transducer, it is difficult to evaluate the mechanical properties of CNT reinforced nanofibers. In this study, CNT/PLA nanofibers were fabricated by the electrospinning method using the electrical potentials difference between two Cu strips of target and the mechanical properties of CNT/PLA nanofiber were evaluated. The morphology of the composite fibers and the dispersion of the CNT within the fibers were observed using transmission electron microscopy (TEM). The tensile test of PLA and CNT/PLA single nanofiber were successfully conducted using a nano-scale tensile testing machine. The tensile strength of PLA and CNT
碳纳米管增强聚乳酸纳米纤维制备工艺的发展及其力学性能评价
由于纳米纤维具有较高的比表面积和体积比,因此有望在组织工程、过滤介质和复合材料增强等方面得到广泛的应用。静电纺丝技术是制备纳米纤维的一种简单方法。在这种技术中,聚合物溶液从针孔中吹出,同时在聚合物溶液和目标之间施加电场。在静电纺丝过程中,溶剂蒸发,聚合物纳米纤维在靶材上制备。为了给纳米纤维添加特殊的功能,研究人员将碳酸钙和TiO2等功能粒子作为纳米纤维的纳米填料。碳纳米管(CNT)具有优异的力学、电学、耐化学性和电磁性能,是块体高分子树脂的增强材料,有望成为一种增强纳米填料。然而,由于操作极小的纤维、制备单纳米纤维样品和寻找精确灵敏的力传感器等挑战,很难评估碳纳米管增强纳米纤维的力学性能。本研究采用静电纺丝法,利用靶材两铜带之间的电位差制备了CNT/PLA纳米纤维,并对纳米纤维的力学性能进行了评价。利用透射电子显微镜(TEM)观察了复合纤维的形态和碳纳米管在纤维中的分散情况。利用纳米尺度拉伸试验机成功地进行了PLA和CNT/PLA单纳米纤维的拉伸试验。PLA和CNT的抗拉强度
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