APPLICATION OF THE METHOD MATHEMATICAL PLANNING EXPERIMENT IN THE PROCESS OF ACTIVATION PEACH SHELLS

А.К. Мamyrbekova, А.D. Мamitova, М.К. Кassymova
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Abstract

For quantitative assessment of influence certain factors on the activation process of peach shells, for obtaining its mathematical model, as well as factors definition at which a developed porous structure is achieved, the method of planning and statistical processing experiment was used in the work. The use of effective methods for regulating the porous structure of activated carbon sorbent suggests that it is possible and economically feasible to use them as adsorbents for the treatment of natural and wastewater and gas emissions. The Box-Wilson experimental-statistical method of planning experiment was used. Modeling by the experimental-statistical Box-Wilson method was carried out in three stages: the first stage is a local description of a small section of the response surface by a polynomial of the first degree; the second stage is a steep ascent along the response surface, which is a geometric interpretation of the response function; the third stage is the approximation of the response surface by a polynomial of the second order. In the work, optimization was carried out by the method of steep ascent over the response surface. The solution of the optimization problem and the finding of a second-order equation were considered. As a result of mathematical modeling of the activation process of adsorbents by the experimental statistical Box-Wilson method, optimal factors of the activation process of peach shells with zinc chloride concentration of 38.2% and an activation temperature in the CO2 stream of 743 K were found.
数学规划实验方法在桃壳活化过程中的应用
为了定量评价影响桃壳活化过程的因素,获得桃壳活化过程的数学模型,以及形成成熟多孔结构的因素定义,采用了规划与统计处理实验的方法。利用有效的方法调节活性炭吸附剂的多孔结构表明,将其作为吸附剂用于自然、废水和气体排放的处理是可能的和经济可行的。采用计划实验的Box-Wilson实验-统计方法。实验统计Box-Wilson方法的建模分三个阶段进行:第一阶段是用一次多项式对响应面的一小部分进行局部描述;第二阶段是沿响应面陡升,这是响应函数的几何解释;第三阶段是用二阶多项式逼近响应面。在工作中,采用响应面陡坡法进行优化。考虑了优化问题的求解和二阶方程的求解。采用实验统计Box-Wilson方法对吸附剂的活化过程进行了数学建模,得到了氯化锌浓度为38.2%、CO2流中活化温度为743 K时桃壳活化过程的最佳因子。
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