Delamination between dielectric layers of FOPLP due to copper residue under high temperature storage conditions

Yeonseop Yu, J. Ha, Mijin Park, Eunju Yang, Miyang Kim
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Abstract

The fan-out panel level package (FOPLP) has its advantage of higher throughput over the fan-out wafer level packages (FOWLP) due to its bigger panel size. It is, however, difficult to maintain uniform quality throughout the panel and secure reliability because there are multiple redistribution layers (RDL) of organic dielectric layers and copper (Cu) conducting paths. In particular, adhesion at various interfaces such as polymer-polymer, polymer-metal, and metal-metal is of great concern because both polymer, and Cu are vulnerable to oxidation at high temperatures in the atmospheric environment. In the present study, we investigated the influence of Cu residue on the degradation of interfacial adhesion in FOPLP under high temperature storage (HTS) conditions. The microstructure and chemistry at the interface were studied using a focused ion beam (FIB) and a transmission electron microscope (TEM). We found that trace amounts of Cu residues prevented two polymers from intermingling during lamination, which is evidenced by accumulation of organosilicon compounds at the interface. We also observed that cracks occurred at the polymer-polymer interface where the Cu residues were present after the HTS test. We propose that the Cu residues should be related to oxidation of polymers at the interfaces during the HTS test and subsequent interfacial delamination.
在高温贮存条件下,由于铜残留而导致的FOPLP介电层之间的分层
由于面板尺寸更大,扇出面板级封装(FOPLP)比扇出晶圆级封装(FOWLP)具有更高的吞吐量优势。然而,由于存在多个有机介电层和铜(Cu)导电路径的再分布层(RDL),因此很难保持整个面板的均匀质量和安全可靠性。特别是,聚合物-聚合物、聚合物-金属、金属-金属等不同界面上的粘附性是非常值得关注的,因为聚合物和铜在大气环境中的高温下都容易氧化。在本研究中,我们研究了Cu残留对高温储存(HTS)条件下FOPLP界面粘附降解的影响。利用聚焦离子束(FIB)和透射电子显微镜(TEM)研究了界面的微观结构和化学性质。我们发现,在层压过程中,微量的Cu残留物阻止了两种聚合物的混合,这可以通过界面上有机硅化合物的积累来证明。我们还观察到,高温超导测试后,在Cu残留物存在的聚合物-聚合物界面处出现了裂纹。我们认为Cu残留物应该与高温超导测试过程中聚合物在界面上的氧化和随后的界面分层有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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