Unique Mixture of (MgO-CdO) Nanoparticles as an Adsorbent for Water Treatment

Wejdan A. Radhi, Zainab T. Y. Alabdullah
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Abstract

Sol- gel method of synthesis of nanomaterials. Sol gel was applied for synthesis of magnesium oxide (MgO) and cadmium oxide (CdO) nanoparticles. Using magnesium nitrate and cadmium acetate as a raw materials and sodium hydroxide as a solvent for hydrated oxide at room temperature. Hydrated Magnesium oxide and cadmium oxide nanoparticles were annealed in air at 600 °C. The characterization methods include examine the morphology of the oxides surface using field emission scanning electron microscopy (FESEM) and Energy Dispersive X-ray spectroscopy (EDX), Characterization of functional groups was performed using Fourier Transform Infrared analysis (FTIR). X-ray powder diffraction (XRD) was used for examine the size of particles using Debye-Scherrer method. MgO and CdO nanoparticles are produced into spherical structures with average crystallite sizes of (55) and (55.5) nm, respectively. The study of using these nanoparticles as adsorbents were done successfully and the high value of removing percentage of iron about 97.8% and 98.7 respectively. Moreover, the mixture of these nano oxides gives 99.2% releasing of iron ion from polluted water.
独特的(MgO-CdO)纳米颗粒混合物作为水处理的吸附剂
溶胶-凝胶法合成纳米材料。采用溶胶凝胶法合成氧化镁(MgO)和氧化镉(CdO)纳米颗粒。以硝酸镁和醋酸镉为原料,氢氧化钠为溶剂,在室温下制备水合氧化物。将水合氧化镁和氧化镉纳米颗粒在空气中600℃退火。表征方法包括使用场发射扫描电镜(FESEM)和能量色散x射线能谱(EDX)检测氧化物表面形貌,使用傅里叶变换红外分析(FTIR)表征官能团。采用x射线粉末衍射(XRD)法测定了颗粒的大小。制备的MgO和CdO纳米颗粒呈球形结构,平均晶粒尺寸分别为(55)nm和(55.5)nm。实验结果表明,采用纳米颗粒作为吸附剂,对铁的去除率分别达到97.8%和98.7%。此外,这些纳米氧化物的混合物使污染水中的铁离子释放率达到99.2%。
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