Transient Photoconductivity in Thin Films of Ferrocene Carboxylic Acid

Chandra Prayaga, C. Mungan, L. Chow
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Abstract

Organic thin films have been actively studied since the early 1980s for photonic applications, due to their large, ultrafast nonlinear optical and electro-optic coefficients, as well as their stability and their ability to be molecularly engineered. Many of the most interesting applications depend on charge transport of the delocalized π electrons in the medium, and hence are influenced by the electronic mobility and the presence of optically active traps [1]. The incorporation of metal ions into the organic compounds enhances their optical nonlinearities. Photoconductivity is also directly related to the mobility of photo-excited charge carriers, their lifetimes, and the recombination mechanisms, and has applications such as in optoelectronic switching and optical detection [2].
二茂铁羧酸薄膜的瞬态光导电性
自20世纪80年代初以来,由于有机薄膜具有大的、超快的非线性光学和电光系数,以及它们的稳定性和分子工程能力,它们在光子应用方面得到了积极的研究。许多最有趣的应用依赖于介质中离域π电子的电荷输运,因此受到电子迁移率和光学活性陷阱[1]的存在的影响。金属离子的掺入增强了有机化合物的光学非线性。光电导率也直接关系到光激发载流子的迁移率、它们的寿命和复合机制,在光电开关和光学探测等领域有广泛的应用。
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