EFFECT OF 5 WT.% WPCB POWDER AS REDUCTANT ON INDONESIAN NICKELIFEROUS ORE PROCESSING

R. M. Ulum, Dimas Ananda Radhitya, A. F. Madsuha, F. Abidin
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Abstract

EFFECT OF 5 WT.% WPCB POWDER AS REDUCTANT ON INDONESIAN LIMONITICNICKEL ORE PROCESSING. Waste printed circuit boards (WPCB) are among the most valuable parts of electronic waste with one of the fastest-growing waste streams in the world. The purpose of this study is to investigate the possibility of WPCB powder as an alternative reducing agent for the carbothermic process in nickel lateritic ore processing. WPCB waste was mixed with nickel ore at 1100ÚC in inert atmosphere. In addition, a conventional reductant of coal is also utilized for comparison. Both reductant are varied in concentration of 5 wt% and 15 wt%. Based on thermogravimetric analysis (TGA) and differential thermogravimetric analysis (DTA) investigation, it is observed that there exists a difference between WPCB powder, nickeliferous ore powder, and the mixture in their decomposed levels. The decomposed gasses of WPCB produced by thermal degradation in the TGA instrument are mainly composed of reduction gas, which plays a critical role in reducing the nickeliferous ore. This study shows that WPCB powder performs comparably to sub-bituminous coal in the pyrometallurgical processing of nickel ore, which is proved by X-Ray Diffraction (XRD) test results that the carbothermic products consists of FeNi, magnetite, wustite and fayalite. It can be concluded than WPCB powder has potential to be utilize as an alternative reductant.
5 wt. % WPCB粉作还原剂对印尼镍矿石加工的影响
5 wt. % WPCB粉作还原剂对印尼锂镍矿加工的影响。废弃印刷电路板(WPCB)是电子废物中最有价值的部分之一,是世界上增长最快的废物流之一。本研究的目的是探讨WPCB粉体作为碳热法处理红土镍矿的备选还原剂的可能性。在1100ÚC惰性气氛下,将WPCB废弃物与镍矿石混合。此外,还使用了一种常规的煤还原剂进行比较。两种还原剂的浓度分别为5wt %和15wt %。通过热重分析(TGA)和差热重分析(DTA)研究,发现WPCB粉、含镍矿粉及其混合物在分解水平上存在差异。热重分析仪热降解WPCB产生的分解气体主要由还原气体组成,在还原含镍矿石中起着至关重要的作用。本研究表明,WPCB粉体在镍矿石的火法冶炼过程中表现与亚烟煤相当,通过x射线衍射(XRD)测试结果证明,其碳热产物主要由FeNi、磁铁矿、浮氏体和铁矾石组成。结果表明,WPCB粉具有作为一种替代还原剂的潜力。
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