Dielectric and pyroelectric properties of a new family of modified polypeptide films

D. Damjanovic, A. Bhalla, L. Cross, S. Erhan, A. Reddy
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Abstract

The dielectric and pyroelectric properties of gelatin-based synthetic polypeptides were studied for possible sensor applications. Among the compositions examined, gelatin films modified with triglycerol were found to have particularly interesting properties. The films exhibited a strong dispersion in the dielectric permittivity accompanied by a high dielectric loss near room temperature. The possible relaxational mechanisms responsible for the observed dielectric behavior are discussed. The pyroelectric properties of the films were investigated. The measurements performed on prepoled samples proved the presence of a true, reversible pyroelectric response in the films. The value of the pyroelectric coefficient of the films was found to be comparable to that of PVDF polymer.<>
一类新型改性多肽薄膜的介电和热释电性质
研究了基于明胶的合成多肽的介电和热释电性质,以用于可能的传感器应用。在研究的组合物中,用甘油三酯修饰的明胶薄膜被发现具有特别有趣的性质。薄膜在室温附近表现出强烈的介电常数色散,并伴有高介电损耗。讨论了引起所观察到的介电行为的可能弛豫机制。研究了薄膜的热释电性能。在预极化样品上进行的测量证明了薄膜中存在真实的、可逆的热释电响应。发现膜的热释电系数值与PVDF聚合物相当。
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