SENSORY PROPERTIES OF NANOCOMPOSITES OF ELECTROCONDUCTING POLYMERS TOWARDS TOXIC AND EXPLOSIVE VOLATILE COMPOUNDS

A. V. Mamykin, O. Kukla, A. S. Pavluchenko, L. Matvienko, I. V. Mogylnyi, A. Pud, N. Ogurtsov, Yuriy Noskov
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Abstract

This work is devoted to the study of sensory properties of nanocomposites of electrically conductive polymers towards a number of phosphorus and organochlorine volatile compounds that are simulators of toxic gaseous substances, as well as nitroaromatic simulators of explosive organic substances. Gas sensitivity measurements were performed using an array of chemoresistive sensor microelectrodes covered with thin layers of these nanocomposites. The relative responses was at the level of 4–5%, the detection threshold depending on the type of analyzed toxic substances was from 10 to 100 ppm, the response rate was about 1 minute. The possibility of qualitative identification of toxic and explosive substances in a wide range of concentrations using the methods of statistical analysis of data from the sensory array has been demonstrated.
导电聚合物纳米复合材料对有毒和爆炸性挥发性化合物的感觉特性
这项工作致力于研究导电聚合物纳米复合材料对一些磷和有机氯挥发性化合物的感觉特性,这些化合物是有毒气体物质的模拟器,以及爆炸性有机物质的硝基芳香模拟器。气敏测量是用一组化学电阻传感器微电极进行的,微电极上覆盖着这些纳米复合材料的薄层。相对响应在4 ~ 5%的水平,检测阈值根据分析的有毒物质类型在10 ~ 100 ppm之间,响应时间约为1分钟。已经证明,利用对来自传感阵列的数据进行统计分析的方法,可以对各种浓度的有毒和爆炸性物质进行定性鉴定。
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