MOF4AIR Project (H2020): Metal Organic Frameworks for Carbon Dioxide Adsorption Processes in Power Production and Energy Intensive Industries

N. Heymans, Marie-Eve Duprez, G. De Weireld
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引用次数: 1

Abstract

Power generation and carbon-intensive industries are responsible of a large share of the anthropogenic CO2 emissions into the atmosphere and play an important role in the greenhouse effect and global warming. Shifting towards a low-carbon economy needs, in addition to reductions at source and use of renewable energy, cost-effective novel carbon capture solution to be conceived, tested and deployed. Current mature solutions either suffer from elevated energy penalties and environmental impacts like in amines-based adsorption and lot of other solutions simply cannot offer sufficient performances. Adsorption processes are promising alternatives for capturing CO2 from power plants and other energy intensive industries as cement, steel or petrochemical industries.

In this regard, Metal Organic Frameworks (MOFs) are a widely studied class of porous adsorbents (recent crystallized porous materials) that offers tremendous potential, owing to their large CO2 adsorption capacity and high CO2 affinity (MOFs can be tuned to create specific adsorption sites associated for trapping CO2). However, the performances of MOF-based carbon capture technologies have not been fully evaluated with flue gases on industrial sites.

In this context, the MOF4AIR project (H2020 LC-SC3-NZE-1-2018) gathers 14 partners from 8 countries and aims to develop, validate and demonstrate the performances of MOF-based CO2 capture technologies (VPSA and MBTSA) in power plants and energy intensive industries. The developed capture solutions will be demonstrated in real environment (TRL 6) on 3 demonstration sites. MOF4AIR aims to foster the uptake of CCUS technologies by providing a TRL6-reliable solution matching end users' needs. The solutions developed will be highly replicable thanks to the consideration of a wide range of carbon intensive sectors and clusters.
MOF4AIR项目(H2020):用于电力生产和能源密集型工业二氧化碳吸附过程的金属有机框架
发电和碳密集型工业在人为排放到大气中的二氧化碳中占很大比例,在温室效应和全球变暖中起着重要作用。向低碳经济转型,除了需要从源头上减少碳排放和使用可再生能源外,还需要构思、测试和部署具有成本效益的新型碳捕获解决方案。目前成熟的解决方案要么存在能量损失和环境影响,比如胺基吸附,而许多其他解决方案根本无法提供足够的性能。吸附法是一种很有前途的替代方法,可以从发电厂和其他能源密集型工业(如水泥、钢铁或石化工业)中捕获二氧化碳。在这方面,金属有机框架(mof)是一类被广泛研究的多孔吸附剂(最近结晶的多孔材料),由于其大的二氧化碳吸附能力和高的二氧化碳亲和力(mof可以调整为创建与捕获二氧化碳相关的特定吸附位点),它提供了巨大的潜力。然而,基于mof的碳捕集技术的性能尚未在工业场所的烟气中得到充分评价。在此背景下,MOF4AIR项目(H2020 LC-SC3-NZE-1-2018)聚集了来自8个国家的14个合作伙伴,旨在开发、验证和展示基于mof的二氧化碳捕集技术(VPSA和MBTSA)在发电厂和能源密集型行业的性能。开发的捕获解决方案将在3个示范点的真实环境(TRL 6)中进行演示。MOF4AIR旨在通过提供符合最终用户需求的trl6可靠解决方案,促进CCUS技术的采用。由于考虑到广泛的碳密集型行业和集群,开发的解决方案将具有高度可复制性。
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