On the Influence of Carbon Nanotubes on the Physical and Mechanical Properties of Polypropylene

Irina Zaporotskova, V. Kalinichenko, L. Kozhitov, P. Zaporotskov, T. Kislova
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Abstract

One of the most interesting and promising materials of our time is carbon nanotubes. Most applications of nanotubes are associated with the possibility of combining them with other materials in the form of alloys, mixtures, composites or hybrid materials. In particular, the idea of including carbon nanotubes as a filler in various polymer-based matrices (for example, traditional polymers such as thermoplastics, thermosetting materials or elastomers, as well as conjugated polymers) for the formation of polymer/carbon nanotube nanocomposites has revolutionized materials science and engineering. The introduction of carbon nanotubes into the composite structure affects the structure and properties of the polymer binder, as well as the composite material as a whole. Currently, there are no experimental developments on the basis of which the introduction, distribution and stabilization of the dispersion of carbon nanotubes in polymer composites would be implemented in industrial technology. The development of the most effective methods for introducing carbon nanotubes into polymer materials and determining their effect on the physical and mechanical properties of polymers is an urgent and priority task. It is possible that these methods will be able to find application in the industrial production of polymer composite materials intended for use and operation in various extreme conditions (whether it is high temperatures, erosion, high force exposure or highly acidic/highly alkaline environments). The main physical and mechanical properties of polypropylene samples saturated with carbon nanotubes taken at different concentrations (0; 0.01; 0.05 and 0.1 wt. %), who found that the addition of CNT in large quantities negatively affects the tensile and bending strength limits, which may be associated with an increase in the degree of heterogeneity of the structure and the appearance of large agglomerates, which will be points of stress concentration. With an increase in the mass fraction of carbon nanotubes in the polymer nanocomposite, the tangent of the dielectric loss angle increases, which leads to better conductivity of the sample containing a larger number of nanotubes. This may be due to the fact that nanotubes become conductors of electric current in the volume of the polymer matrix.
碳纳米管对聚丙烯物理力学性能的影响
我们这个时代最有趣和最有前途的材料之一是碳纳米管。纳米管的大多数应用都与它们以合金、混合物、复合材料或杂交材料的形式与其他材料结合的可能性有关。特别是,包括碳纳米管作为填料在各种聚合物基基质(例如,传统聚合物,如热塑性塑料,热固性材料或弹性体,以及共轭聚合物)中形成聚合物/碳纳米管纳米复合材料的想法已经彻底改变了材料科学和工程。在复合材料结构中引入碳纳米管会影响聚合物粘结剂的结构和性能,也会影响复合材料的整体性能。目前,碳纳米管分散体在聚合物复合材料中的引入、分布和稳定在工业技术上还没有实验发展的基础。开发将碳纳米管引入高分子材料并确定其对高分子材料物理力学性能影响的最有效方法是一项紧迫而优先的任务。这些方法有可能在各种极端条件下(无论是高温、侵蚀、高强度暴露还是高酸性/高碱性环境)使用和操作的聚合物复合材料的工业生产中找到应用。碳纳米管饱和聚丙烯样品在不同浓度(0;0.01;0.05和0.1 wt. %),他们发现大量添加碳纳米管会对拉伸和弯曲强度极限产生负面影响,这可能与结构不均匀程度的增加和大团块的出现有关,这将是应力集中的点。随着碳纳米管在聚合物纳米复合材料中质量分数的增加,介质损耗角的正切角增加,导致含有更多碳纳米管的样品具有更好的导电性。这可能是由于纳米管在聚合物基质的体积中成为电流的导体。
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