Microstructural, Mechanical and Electrochemical Characterization of a Flame Sprayed NiFeCrBSi/WC Cermet Coating

Rabah Azzoug, Y. Mebdoua, F. Hellal
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Abstract

To increase the lifetime of drilling bits, these components are usually covered with hard metal matrix composites. Nowadays, nickel based metal matrix composites arise as substitutes to cobalt-based ones. The challenge now is to provide an efficient coating with low cost. The aim of this paper is to exploit the characteristics of a newly designed flame sprayed NiFeCrBSi-WC composite coatings. The experimental activities were carried out using the scanning electron microscopy, for the microstructural analysis of coating. Additionally, micro-hardness and nano-indentation tests were carried out to evaluate the resistance of the coatings against penetration. Moreover, the electrochemical behavior was assessed in NaCl and Na2SO4 aqueous solutions. The ionic concentrations were varied between 1 g/l to 35 g/l. The results show that the microstructure is dendritic and characterized by the presence of hard chromium carbides and nickel grains in the inter-dendritic space. The coating was subject to a slight decarburization. The presence of carbides and the decarburization make the microhardness of the matrix fluctuates between 300 HV to 900 HV. For the electrochemical response, the increase in ion concentration induces a decrease in the corrosion resistance. In Na2SO4 aqueous solutions, the charge transfer is roughly constant for the concentrations above 1 g/l.
火焰喷涂NiFeCrBSi/WC陶瓷涂层的显微组织、力学和电化学表征
为了延长钻头的使用寿命,这些部件通常用硬质金属基复合材料覆盖。目前,镍基金属基复合材料作为钴基复合材料的替代品而兴起。现在的挑战是提供一种低成本的高效涂层。本文的目的是开发新设计的火焰喷涂NiFeCrBSi-WC复合涂层的特性。采用扫描电镜对涂层进行了显微组织分析。此外,还进行了显微硬度和纳米压痕测试,以评估涂层的抗渗透性能。并对其在NaCl和Na2SO4水溶液中的电化学行为进行了评价。离子浓度在1 g/l ~ 35 g/l之间变化。结果表明:该合金的显微组织为枝晶,枝晶间存在硬质碳化铬和镍晶粒;涂层发生了轻微的脱碳。碳化物的存在和脱碳使基体的显微硬度在300 ~ 900 HV之间波动。对于电化学响应,离子浓度的增加导致耐蚀性的降低。在Na2SO4水溶液中,当浓度大于1g /l时,电荷转移基本保持不变。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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