Addition Of Chain Extender To Improve Flexible Polyurethane Foam Characteristics Of Palm Oil Polyol

Neswati -, N. Nazir, S. Arief, Yurniwati
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Abstract

The use of 100% palm oil polyol without the addition of a chain extender produced foam which initially expands and then collapses so that the resulting foam has tight pores, dense texture, and brittle (brittle). It was necessary to use a chain extender to improve the flexible properties of the foam. This study aimed to examine the ratio of palm oil polyols with a chain extender to produce flexible polyurethane foam with good characteristics. The treatment of this study was a combination of types and comparisons of palm oil polyols with chain extenders which were carried out 3 times, consisting of factor A = type of chain extender (diethylene glycol (DEG), diethanolamine (DEA), and polyethylene glycol (PEG)-400) and factor B = ratio of palm oil polyols. with a chain extender (80%:20%; 70%:30%; 60%:40%; 50%:50%). The obtained foam was observed visually, foam development, and foam density. The best sample for each type of extender was analyzed by FTIR. The results showed that 40% PEG-400 has succeeded in producing flexible polyurethane foam with higher expansion (291.22%), lower density (29 kg/m3), and visually has the best flexible properties. Based on FTIR analysis, the use of PEG-400 in the polyol system can increase the reactivity of palm oil polyols to isocyanates.
添加扩链剂改善棕榈油多元醇柔性聚氨酯泡沫特性
使用100%棕榈油多元醇而不添加扩链剂产生的泡沫最初膨胀,然后收缩,因此产生的泡沫毛孔紧致,质地致密,易碎(脆)。为了提高泡沫的柔韧性,有必要使用扩链剂。本研究旨在研究棕榈油多元醇与扩链剂的配比,以生产出性能良好的柔性聚氨酯泡沫。本研究的处理方法是结合棕榈油多元醇与扩链剂的种类和比较,共进行3次,包括因子a =扩链剂的种类(二甘醇(DEG)、二乙醇胺(DEA)和聚乙二醇(PEG)-400),因子B =棕榈油多元醇的比例。加扩链剂(80%:20%;70%: 30%;60%: 40%;50%: 50%)。对所得泡沫进行目测、泡沫发育和泡沫密度观察。用傅里叶变换红外光谱分析了每种增稠剂的最佳样品。结果表明:掺量为40%的PEG-400成功制得膨胀率较高(291.22%)、密度较低(29 kg/m3)的柔性聚氨酯泡沫,且在视觉上具有最佳的柔性性能。FTIR分析表明,在多元醇体系中使用PEG-400可以提高棕榈油多元醇对异氰酸酯的反应性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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