Synthesis and Characterization of Luminescent Thin Films Based on Nd3+-Doped YAG Nanocrystals in Silica Microstructured Optical Fibers for Sensing Applications

A. Matrosova, N. Kuzmenko, S. Evstropiev, G. Pchelkin, D. Bulyga, N. Nikonorov
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Abstract

We suggested an alternative to technically complex CVD processes method for producing thin films containing highly luminescent YAG nanocrystals activated with Nd3+ ions inside channels of microstructured optical fibers by the liquid polymer-salt method. As a result of studying structural and spectral properties of the obtained optical elements, the formation of highly luminescent in the near-IR region nanocrystals was determined, which defines the potential of their application in sensor technologies. We studied temperature sensitivity of YAG:Nd3+ nanocrystals synthesized in channels of a microstructured optical fiber and compared it with YAG:Nd3+ nanocrystals having the form of powder. It was found out that luminescence intensity of these materials decreases exponentially in the temperature range from 50 to 600 °C.
传感用二氧化硅微结构光纤中Nd3+掺杂YAG纳米晶体发光薄膜的合成与表征
我们提出了一种替代技术复杂的CVD工艺方法,通过液体聚合物-盐方法在微结构光纤通道内制备含有高发光的YAG纳米晶体的薄膜,这些纳米晶体被Nd3+离子激活。通过对获得的光学元件的结构和光谱特性的研究,确定了在近红外区域形成高度发光的纳米晶体,这确定了其在传感器技术中的应用潜力。研究了在微结构光纤通道中合成的YAG:Nd3+纳米晶体的温度敏感性,并将其与粉末形式的YAG:Nd3+纳米晶体进行了比较。结果表明,在50 ~ 600℃的温度范围内,这些材料的发光强度呈指数衰减。
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