Nanostructured CVD W/WC Coating Protects Steam and Gas Turbine Blades Against Water Droplet Erosion

Y. Zhuk
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Abstract

Gas turbine compressor blades operating with air inlet fogging can suffer from Water Droplet Erosion (WDE). WDE can also affect the last rows of steam turbines where expanding steam produces water condensation, especially under start-up and low load conditions. WDE damages the blades’ leading and sometimes trailing edges, increasing turbine rotation drag, reducing efficiency and leading to costly maintenance. This paper reports the testing of Hardide® nano-structured W/WC metal matrix composite coating as a protection against WDE. The Chemical Vapor Deposition (CVD) technology crystallizes the coating atom-by-atom from the gas phase and produces a uniform pore-free coating on complex shaped parts like turbine blades, vanes and pump impellers, including non-line-of-sight areas. Two variants of CVD W/WC coatings were tested: “A” type is 50–100 microns thick and has a hardness range of 800–1200 Hv and “T” type is 35–65 microns thick with a higher hardness of 1100–1600 Hv. Both coating types are made of Tungsten Carbide nanoparticles dispersed in metal Tungsten matrix. This composition and structure produce a combination of enhanced fracture toughness with high hardness and enables the deposition of exceptionally thick hard CVD coatings to provide durable protection against WDE and solid particle erosion. The coatings are pore-free thus also provide an effective barrier against corrosion. The coatings were tested for WDE resistance by the UK National Physics Laboratory (NPL) using 350 μm water droplets at 300 m/sec velocity. Uncoated 410 SS control samples suffered from a major loss of material after just 7-hours of exposure to WDE, forming a 200 μm deep scar across the whole tested area. After a much longer exposure of 90 hours, the coating samples showed negligible WDE damage, only measurable on the samples’ edges. The coating also outperformed Stellite, which is widely used as WDE protection in the form of welded overlay or plates brazed to the blade’s leading edge. The thicker and less hard type “A” CVD coating showed better performance when compared to the thinner, harder type “T”. The effects of the coatings’ thickness, hardness, and residual stresses on the WDE resistance are discussed. The rig testing showed that the CVD WC/W coating can protect steam and gas turbine blades against WDE thus increasing the service life of equipment and maintaining its optimal performance for longer, reducing CO2 emissions and cutting the life-cycle costs. Hardide coatings are used by major oil service companies, pump and valve producers to improve durability in abrasive and corrosive environments. Airbus has approved Hardide-A coating as a REACH-compliant replacement for Hard Chrome plating on aircraft components. Other customers include BAE Systems, EDF Energy, Leonardo Helicopters and Lockheed Martin. The Hardide coating service is provided from state-of-the-art coating facilities near Oxford (UK) and in Virginia (US). Production and quality control are accredited to ISO9001, AS9100 and NADCAP standards.
纳米结构CVD W/WC涂层保护蒸汽和燃气轮机叶片免受水滴侵蚀
燃气轮机压气机叶片在进气雾化条件下运行时,会受到水滴侵蚀(WDE)的影响。WDE还可以影响汽轮机的最后几排,在那里膨胀的蒸汽产生冷凝水,特别是在启动和低负荷条件下。WDE会破坏叶片的前缘,有时还会破坏叶片的尾缘,增加涡轮机的旋转阻力,降低效率,并导致昂贵的维护费用。本文报道了Hardide®纳米结构钨/碳化钨金属基复合涂层作为WDE防护的测试。化学气相沉积(CVD)技术将涂层从气相中原子一个原子地结晶,并在复杂形状的部件(如涡轮叶片、叶片和泵叶轮)上产生均匀的无孔涂层,包括非视线区域。测试了两种CVD W/WC涂层:“A”型涂层厚度为50-100微米,硬度范围为800-1200 Hv;“T”型涂层厚度为35-65微米,硬度范围为1100-1600 Hv。两种类型的涂层都是由分散在金属钨基体中的碳化钨纳米颗粒制成的。这种成分和结构结合了增强的断裂韧性和高硬度,使沉积特别厚的硬质CVD涂层能够提供持久的保护,防止WDE和固体颗粒侵蚀。涂层是无孔的,因此也提供了一个有效的防腐蚀屏障。英国国家物理实验室(NPL)利用350 μm水滴以300 m/秒的速度测试了涂层的WDE抗性。未涂覆的410 SS对照样品在暴露于WDE仅7小时后就遭受了严重的材料损失,在整个测试区域形成了200 μm深的疤痕。在90小时的长时间暴露后,涂层样品显示出可以忽略不计的WDE损伤,仅在样品的边缘可测量。该涂层也优于钨铬钴合金,钨铬钴合金被广泛用作WDE保护,以焊接覆盖层或钢板钎焊到叶片前缘。厚度较厚、硬度较低的“A”型CVD涂层比厚度较薄、硬度较硬的“T”型CVD涂层表现出更好的性能。讨论了涂层的厚度、硬度和残余应力对抗WDE性能的影响。试验表明,CVD WC/W涂层可以保护蒸汽和燃气轮机叶片免受WDE的影响,从而延长设备的使用寿命,并更长时间地保持其最佳性能,减少二氧化碳排放,降低生命周期成本。Hardide涂层被主要的石油服务公司、泵和阀门生产商使用,以提高在磨蚀和腐蚀性环境中的耐久性。空中客车公司已批准Hardide-A涂层作为符合reach标准的飞机部件镀硬铬的替代品。其他客户包括BAE系统公司、EDF能源公司、莱昂纳多直升机公司和洛克希德马丁公司。Hardide涂层服务由位于牛津(英国)和弗吉尼亚(美国)附近的先进涂层设施提供。生产和质量控制通过ISO9001, AS9100和NADCAP标准认证。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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