Biorefinery based on different vegetable oils: characterization of biodiesel and biolubricants

J. Encinar, S. Nogales, J. F. González
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引用次数: 2

Abstract

The search for alternative and eco-friendly products such as biodiesel and biolubricants, as substitutes for petroleum-based products, is becoming more and more important. Thus, the production of biodiesel and biolubricants could be interesting, as it is based on renewable sources such as seed or fried used oils. For this reason, the use of vegetable oils could be important for the design of biorefineries, where many by-products could also be reused in the same biorefinery. The aim of this research work was to study the production of biodiesel and, especially, biolubricants from different raw materials (with the subsequent characterization), paying attention to their characteristics and their possible suitability for their production in a biorefinery. This way, optimum chemical conditions were used to carry out the transesterification of biodiesel and biolubricants. Concerning the production, high yields were obtained in all cases. Some characteristics were studied, such as fatty acid methyl ester profile, viscosity and oxidative stability, among others. Biodiesel products complied with the standards, concerning the main characteristics covered in this research work. Regarding biolubricants, in general, viscosity values were similar to those found in the literature, but longer induction points were found. In that sense, these parameters were highly influenced by the fatty acid profile of the raw material, which is important for both biodiesel and biolubricant performance. Therefore, the initial characterization of vegetable oils is important for the design of biorefineries.
基于不同植物油的生物炼制:生物柴油和生物润滑剂的特性
寻找替代和环保产品,如生物柴油和生物润滑剂,作为石油基产品的替代品,正变得越来越重要。因此,生物柴油和生物润滑剂的生产可能是有趣的,因为它是基于可再生资源,如种子或油炸废油。出于这个原因,植物油的使用对于生物精炼厂的设计可能很重要,因为许多副产品也可以在同一生物精炼厂中重复使用。这项研究工作的目的是研究从不同原料生产生物柴油,特别是生物润滑剂(以及随后的表征),关注它们的特性及其在生物精炼厂中生产的可能适用性。通过这种方法,利用最优的化学条件进行生物柴油和生物润滑剂的酯交换反应。在生产方面,所有情况下都获得了较高的产量。研究了油脂的脂肪酸甲酯谱、粘度、氧化稳定性等特性。生物柴油产品符合标准,涉及本研究工作的主要特点。对于生物润滑剂,总体上粘度值与文献中发现的相似,但诱导点更长。从这个意义上说,这些参数受到原料脂肪酸分布的高度影响,这对生物柴油和生物润滑剂的性能都很重要。因此,植物油的初步表征对生物炼油厂的设计至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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