Sorption of Phosphorus from Fertilizer Mixture

Abstract

Studying phosphorus (P) sorption behavior is among the prerequisites for P management in the crop fields. The work presented in this chapter described P sorption data when fertilizer mixture (NH 4 NO 3 , KH 2 PO 4 , and KCl) was used to characterize sorption on soil. In addition to using fertilizer mixture, sorption experiments were also conducted using KH 2 PO 4 prepared in 0.01 M KCl, 0.005 M CaCl 2 , and deionized water. The 24-h batch sorption experiments were conducted using a sandy soil to solution ratio of 1:2, and the equilibrium solution and sorbed data were described using Freundlich isotherm. Sorption kinetics experiments were conducted using times, 4, 8, 12, and 24 h. The Freundlich isotherm constant and sorbed P kinetics data for 0.005 M CaCl 2 were significantly greater ( p < 0.05) than for 0.01 M KCl and/or fertilizer mixture. The Freundlich isotherm constant and sorbed P kinetics data for deionized water were significantly lower ( p < 0.05) than for 0.01 M KCl and/or fertilizer mixture. There was no significant difference in Freundlich isotherm constant and sorbed P kinetics data for 0.01 M KCl and fertilizer mixture. The sorption data showed the importance of using the fertilizer mix applied to the field when conducting sorption experiments.