Eco-friendly production of silica particles and fertilizer from rice husk, rice straw, and corncob wastes

Rafiq Usdiqa Maulana, Sania Isma Yanti, Riyanti Zhafirah Makrudi, T. Mahatmanto, U. Murdiyatmo
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Abstract

Agroindustrial wastes represent a rich and underutilized source of valuable minerals. Because the amount of biomass wastes generated by the agroindustry is increasing and the demand for sustainability is arising, there is a growing need for improving agroindustrial waste utilization and valorization. One of the major industrial interests has been obtaining silica from biomass wastes. The synthesis of silica from agroindustrial waste materials typically involves the use of high energy input for calcination or incineration and chemicals for extraction. To reduce energy consumption and chemical waste generation, we modified a sol-gel method to yield a by-product that can be used as a fertilizer. High purity silica was obtained from rice husk (95.1%), rice straw (91.4%), and corncob (95.9%). The silica particles were amorphous and white in color. The mean diameters of the silica particles obtained from rice husk, rice straw, and corncob were 72.4, 68.1, and 52.9 µm, respectively. The acid waste generated from the process was neutralized to yield potassium chloride. This by-product had mineral contents that could be used for inorganic fertilizer. In addition to supporting sustainability, the development of agroindustrial waste utilization methods is important for the establishment of inexpensive processes that are adaptable for large-scale manufacturing.
从稻壳、稻草和玉米芯废料中环保生产二氧化硅颗粒和肥料
农业工业废料是宝贵矿物的丰富而未得到充分利用的来源。由于农业工业产生的生物质废物的数量正在增加,对可持续性的需求正在增加,因此越来越需要改善农业工业废物的利用和增值。从生物质废料中获取二氧化硅已成为主要的工业兴趣之一。从农业工业废料中合成二氧化硅通常涉及使用高能量投入进行煅烧或焚烧,并使用化学品进行提取。为了减少能源消耗和化学废物的产生,我们改进了一种溶胶-凝胶法,以产生一种可以用作肥料的副产品。稻壳(95.1%)、稻草(91.4%)和玉米芯(95.9%)得到了高纯度的二氧化硅。二氧化硅颗粒呈无定形,呈白色。稻壳、稻草和玉米芯中二氧化硅颗粒的平均直径分别为72.4、68.1和52.9µm。该工艺产生的酸性废液经中和后产生氯化钾。这种副产品含有矿物质,可以用作无机肥料。除了支持可持续性外,发展农业工业废物利用方法对于建立适用于大规模制造的廉价工艺也很重要。
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