SYNTHESIS AND CHARACTERIZATION OF SOME MODIFIED EPOXY RESINS WITH FATTY ACIDS

A. M. Al-Hussam, J.K. ALKafaji
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Abstract

Some modified epoxy resins were prepared from the reaction of epoxy resin with some fatty acids (palmitic acid, stearic acid, oleic acid)in the presence of paratoluene Sulfonic acid at low temperature ranging between 70,90C◦ and at high temperature ranging between 280,300C◦. All the epoxy modifiers were characterized by IR and acid value AV. The mechanical properties (Hardness, Impact strength, Elongation, Tensile strength) and thermal stability (TGA) were studied. The mechanical properties of modified are lower than unmodified polymers, but Oleic acid was the best of all. The thermal stability was decreased according to below (Stearic acid> Palmatic acid>Oleic. acid).     
几种脂肪酸改性环氧树脂的合成与表征
在对甲苯磺酸存在下,环氧树脂与某些脂肪酸(棕榈酸、硬脂酸、油酸)在70、90℃之间的低温和280、300℃之间的高温下反应,制备了改性环氧树脂。用IR和酸值AV对改性剂进行表征,研究了改性剂的硬度、冲击强度、伸长率、抗拉强度和热稳定性。改性聚合物的力学性能低于未改性聚合物,但油酸的力学性能最好。热稳定性降低的顺序为:硬脂酸>棕榈酸>油酸。酸)。
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