The study of nanosized zeolite films in sensor for DMMP gas detection

Haifen Xie, Qiong Hu, Jia Zhou, Yipin Huang
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Abstract

Nanosized ZSM-5 and Ag+ modified nanosized ZSM-5 as sensitive films to detect the nerve agent simulant dimethylmethylphosphonate(DMMP) at low concentration has been reported [1]. In order to find the relationship between pore size and sensitivity, larger pore size β zeolite film was also used to detect the DMMP gas. Different types of zeolite films with specific sensitivity towards low concentration of acetone and ethanol gases were discussed. This observation demonstrates that sensitivity depended not only on the size of the molecules but also morphology of zeolite grains. The Ag+ modified nanosized ZSM-5 film has a high sorption capacity of acetone gas, while nanosized ZSM-5 has higher sorption capacity of DMMP gas. β zeolite film had the worst absorption of the DMMP gas. The absorption and desorption condition of nanosized ZSM-5 film was also discussed in this paper. Based on these results it was concluded that nanosized ZSM-5 films could be used as effective DMMP gas sensor materials.
纳米沸石膜用于DMMP气体检测传感器的研究
纳米ZSM-5和Ag+修饰的纳米ZSM-5作为检测低浓度神经毒剂模拟物二甲甲基膦酸盐(DMMP)的敏感膜已有报道[1]。为了找出孔径与灵敏度之间的关系,还采用了孔径较大的β沸石膜来检测DMMP气体。讨论了不同类型的对低浓度丙酮和乙醇气体具有特定敏感性的沸石膜。这一观察结果表明,灵敏度不仅取决于分子的大小,而且取决于沸石颗粒的形态。Ag+修饰的纳米ZSM-5膜对丙酮气体具有较高的吸附能力,而纳米ZSM-5对DMMP气体具有较高的吸附能力。β沸石膜对DMMP气体的吸收效果最差。本文还讨论了纳米ZSM-5薄膜的吸附和解吸条件。结果表明,纳米ZSM-5薄膜可以作为DMMP气体传感器的有效材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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